•Influence of alkyl substituent length on IL properties was studied.•Nature of interactions between studied [CnC1im][NTf2] and GBL were discussed.•Angell strength parameter indicates [CnC1im][NTf2] are fragile liquids.•ILs properties regularly change with increase of the alkyl chain length.•Absence of GBL self-association upon addition of IL is observed.
The Journal of Chemical Thermodynamics – Elsevier
Published: Aug 1, 2016
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