•The HEm of benzene + cyclohexane was measured near vapor pressure curve of benzene.•And was measured in the region between liquid state and state near critical points.•The contour of HEm was created on the p-T plane over a wide range of p and T.•Three-dimensional behavior of HEm are discussed.•HEm reached a local maximum at p and T slightly less than benzene critical point.
The Journal of Chemical Thermodynamics – Elsevier
Published: May 1, 2018
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