The change of representative elementary volume of DNAPL influenced by surface active agents during long-term remediation period in heterogeneous porous media

The change of representative elementary volume of DNAPL influenced by surface active agents... Representative elementary volume (REV) is important to characterize dense nonaqueous phase liquids (DNAPLs) during surfactant-Enhanced aquifer remediation (SEAR) period. To investigate the REVs of DNAPL in remediation, a perchloroethylene (PCE) SEAR experiment is conducted in a two dimensional (2D) heterogeneous translucent porous media. Light transmission techniques are used to quantify PCE saturation (Soil) and PCE-water interfacial area (AOW). Afterward, corresponding REVs are estimated using a criterion of relative gradient error (εgi) to reveal the change of REVs of DNAPL over the entire remediation period. Results from this work suggest the presence of surface active agents strongly affect the REVs of DNAPL. At the beginning of the SEAR experiment, the frequency of minimum Soil-REV size closely follows a Gaussian distribution in 0.0mm–11.0mm. Simultaneously, the frequency of minimum AOW-REV size is close to a Gaussian distribution in 2.0mm–9.0mm and appears a peak value in 13.0mm–14.0mm. As SEAR experiment proceeds, both the shapes of frequency and cumulative frequency of REV sizes are changed. At the end of SEAR experiment, the frequency of minimum Soil-REV and minimum AOW-REV size tend to Gaussian distributions in 0.0mm–6.0mm and 0.0mm–9.0mm, respectively, which suggest both minimum Soil-REV size and minimum AOW-REV size show decreasing tendency. Continuous quantification of the REVs of DNAPL is realized in this study to reveal the change of REVs influenced by surface active agent. The finding has important significance on improving our understanding of the characteristics of DNAPL in SEAR process, simulating DNAPL remediation and designing appropriate remediation scheme with high-resolution. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Science of the Total Environment Elsevier

The change of representative elementary volume of DNAPL influenced by surface active agents during long-term remediation period in heterogeneous porous media

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier B.V.
ISSN
0048-9697
eISSN
1879-1026
D.O.I.
10.1016/j.scitotenv.2018.01.026
Publisher site
See Article on Publisher Site

Abstract

Representative elementary volume (REV) is important to characterize dense nonaqueous phase liquids (DNAPLs) during surfactant-Enhanced aquifer remediation (SEAR) period. To investigate the REVs of DNAPL in remediation, a perchloroethylene (PCE) SEAR experiment is conducted in a two dimensional (2D) heterogeneous translucent porous media. Light transmission techniques are used to quantify PCE saturation (Soil) and PCE-water interfacial area (AOW). Afterward, corresponding REVs are estimated using a criterion of relative gradient error (εgi) to reveal the change of REVs of DNAPL over the entire remediation period. Results from this work suggest the presence of surface active agents strongly affect the REVs of DNAPL. At the beginning of the SEAR experiment, the frequency of minimum Soil-REV size closely follows a Gaussian distribution in 0.0mm–11.0mm. Simultaneously, the frequency of minimum AOW-REV size is close to a Gaussian distribution in 2.0mm–9.0mm and appears a peak value in 13.0mm–14.0mm. As SEAR experiment proceeds, both the shapes of frequency and cumulative frequency of REV sizes are changed. At the end of SEAR experiment, the frequency of minimum Soil-REV and minimum AOW-REV size tend to Gaussian distributions in 0.0mm–6.0mm and 0.0mm–9.0mm, respectively, which suggest both minimum Soil-REV size and minimum AOW-REV size show decreasing tendency. Continuous quantification of the REVs of DNAPL is realized in this study to reveal the change of REVs influenced by surface active agent. The finding has important significance on improving our understanding of the characteristics of DNAPL in SEAR process, simulating DNAPL remediation and designing appropriate remediation scheme with high-resolution.

Journal

Science of the Total EnvironmentElsevier

Published: Jun 1, 2018

References

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