Synthesis and novel fluorescence phenomenon of terbium complex with a new Schiff base ligand derived from condensation of triaminotriethylamine and 3-indolemethanal

Synthesis and novel fluorescence phenomenon of terbium complex with a new Schiff base ligand... A new Schiff base ligand with tripodal structure, N , N ′, N ″-tri-(3-indolemethanal)-triaminotriethylamine (L), and its complex with terbium was synthesized. The complex was characterized by element analysis, IR spectra, mass spectra, thermal analysis and molar conductivity. The terbium ion was found to coordinate to the Schiff base nitrogen atoms and the bridgehead nitrogen atom. The fluorescence properties of the complex in aqueous solutions were studied. Under the excitation of UV light, the complex exhibits characteristic fluorescence of terbium ion. H + concentration could strongly enhance the luminescence of terbium complex with L in aqueous solutions. This phenomenon will make the new complex favorable to be used in the fluorescence switches and sensors. The mechanism of the fluorescence enhancement by protonation of the indole nitrogen atoms is due to the suppressed photoinduced electron transfer (PIET) fluorescence quenching when adding acid. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Elsevier

Synthesis and novel fluorescence phenomenon of terbium complex with a new Schiff base ligand derived from condensation of triaminotriethylamine and 3-indolemethanal

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Publisher
Elsevier
Copyright
Copyright © 2006 Elsevier B.V.
ISSN
1386-1425
D.O.I.
10.1016/j.saa.2006.06.044
Publisher site
See Article on Publisher Site

Abstract

A new Schiff base ligand with tripodal structure, N , N ′, N ″-tri-(3-indolemethanal)-triaminotriethylamine (L), and its complex with terbium was synthesized. The complex was characterized by element analysis, IR spectra, mass spectra, thermal analysis and molar conductivity. The terbium ion was found to coordinate to the Schiff base nitrogen atoms and the bridgehead nitrogen atom. The fluorescence properties of the complex in aqueous solutions were studied. Under the excitation of UV light, the complex exhibits characteristic fluorescence of terbium ion. H + concentration could strongly enhance the luminescence of terbium complex with L in aqueous solutions. This phenomenon will make the new complex favorable to be used in the fluorescence switches and sensors. The mechanism of the fluorescence enhancement by protonation of the indole nitrogen atoms is due to the suppressed photoinduced electron transfer (PIET) fluorescence quenching when adding acid.

Journal

Spectrochimica Acta Part A: Molecular and Biomolecular SpectroscopyElsevier

Published: Jun 1, 2007

References

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