Synthesis and characterization of diorganoantimony(III) and -bismuth(III) halides with 2-(Et2NCH2)C6H4 and 2-(i-Pr2NCH2)C6H4 substituents

Synthesis and characterization of diorganoantimony(III) and -bismuth(III) halides with... Inorganica Chimica Acta 475 (2018) 155–160 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Synthesis and characterization of diorganoantimony(III) and -bismuth (III) halides with 2-(Et NCH )C H and 2-(i-Pr NCH )C H substituents 2 2 6 4 2 2 6 4 a a b a,⇑ Ionuţ Chirca˘ , Cristian Silvestru , Hans Joachim Breunig , Ciprian I. Raţ Supramolecular Organic and Organometallic Chemistry Centre, Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babeș-Bolyai University, 11 Arany Janos, 400028 Cluj-Napoca, Romania Institut für Anorganische und Physikalische Chemie, Fachbereich 02: Biologie/Chemie, Universität Bremen, D-28334 Bremen, Germany article i nfo abstract Article history: Compounds [2-(Et NCH )C H ] SbX [X = Cl (1), Br (2)] and [2-(i-Pr NCH )C H ] EBr [E = Sb (3), Bi (4)] 2 2 6 4 2 2 2 6 4 2 Received 31 July 2017 were prepared by coupling reactions between organolithium derivatives or Grignard reagents and the Received in revised form 7 November 2017 corresponding metal halides. Compounds 1–4 were characterized in solution by multinuclear NMR spec- Accepted 13 November 2017 troscopy, mass spectrometry and their molecular structures were determined by single-crystal X-ray Available online 20 November 2017 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganica Chimica Acta Elsevier

Synthesis and characterization of diorganoantimony(III) and -bismuth(III) halides with 2-(Et2NCH2)C6H4 and 2-(i-Pr2NCH2)C6H4 substituents

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0020-1693
eISSN
1873-3255
D.O.I.
10.1016/j.ica.2017.11.021
Publisher site
See Article on Publisher Site

Abstract

Inorganica Chimica Acta 475 (2018) 155–160 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Synthesis and characterization of diorganoantimony(III) and -bismuth (III) halides with 2-(Et NCH )C H and 2-(i-Pr NCH )C H substituents 2 2 6 4 2 2 6 4 a a b a,⇑ Ionuţ Chirca˘ , Cristian Silvestru , Hans Joachim Breunig , Ciprian I. Raţ Supramolecular Organic and Organometallic Chemistry Centre, Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babeș-Bolyai University, 11 Arany Janos, 400028 Cluj-Napoca, Romania Institut für Anorganische und Physikalische Chemie, Fachbereich 02: Biologie/Chemie, Universität Bremen, D-28334 Bremen, Germany article i nfo abstract Article history: Compounds [2-(Et NCH )C H ] SbX [X = Cl (1), Br (2)] and [2-(i-Pr NCH )C H ] EBr [E = Sb (3), Bi (4)] 2 2 6 4 2 2 2 6 4 2 Received 31 July 2017 were prepared by coupling reactions between organolithium derivatives or Grignard reagents and the Received in revised form 7 November 2017 corresponding metal halides. Compounds 1–4 were characterized in solution by multinuclear NMR spec- Accepted 13 November 2017 troscopy, mass spectrometry and their molecular structures were determined by single-crystal X-ray Available online 20 November 2017

Journal

Inorganica Chimica ActaElsevier

Published: Apr 24, 2018

References

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