Supramolecular architecture of [AsPh2Br2]2[(Br3)−…(Br2)…(Br3)−] obtained by bromination of (AsPh2)2S

Supramolecular architecture of [AsPh2Br2]2[(Br3)−…(Br2)…(Br3)−] obtained by bromination... Inorganica Chimica Acta 475 (2018) 120–126 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Research paper Supramolecular architecture of [AsPh Br ] [(Br ) ...(Br )...(Br ) ] 2 2 2 3 2 3 obtained by bromination of (AsPh ) S 2 2 a,⇑ a a b Luminita Silaghi-Dumitrescu , Amr A.A. Attia , Radu Silaghi-Dumitrescu , Alexander J. Blake , D. Bryan Sowerby Department of Chemistry, Babes-Bolyai University, 1, Kogalniceanu Str., 400084 Cluj-Napoca, Romania School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom ar ti c l e i nf o ab stra ct Article history: Bromination of (AsPh ) S leads to cleavage of the sulfide bridge to give AsPh Br when 1 mol of bromine is 2 2 2 Received 30 July 2017 used but with 2 mols the product is the polybromide, [AsPh Br ] [Br ], containing the previously 2 2 2 8 Received in revised form 21 August 2017 + unknown [AsPh Br ] cation and a rare [(Br ) ...(Br )...(Br ) ] ensemble whose short (yet not covalent) 2 2 3 2 3 Accepted 25 August 2017 2 Br ...Br contacts have previously supported tentative description http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganica Chimica Acta Elsevier

Supramolecular architecture of [AsPh2Br2]2[(Br3)−…(Br2)…(Br3)−] obtained by bromination of (AsPh2)2S

Loading next page...
 
/lp/elsevier/supramolecular-architecture-of-asph2br2-2-br3-br2-br3-obtained-by-zBr22syVb1
Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0020-1693
eISSN
1873-3255
D.O.I.
10.1016/j.ica.2017.08.052
Publisher site
See Article on Publisher Site

Abstract

Inorganica Chimica Acta 475 (2018) 120–126 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Research paper Supramolecular architecture of [AsPh Br ] [(Br ) ...(Br )...(Br ) ] 2 2 2 3 2 3 obtained by bromination of (AsPh ) S 2 2 a,⇑ a a b Luminita Silaghi-Dumitrescu , Amr A.A. Attia , Radu Silaghi-Dumitrescu , Alexander J. Blake , D. Bryan Sowerby Department of Chemistry, Babes-Bolyai University, 1, Kogalniceanu Str., 400084 Cluj-Napoca, Romania School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom ar ti c l e i nf o ab stra ct Article history: Bromination of (AsPh ) S leads to cleavage of the sulfide bridge to give AsPh Br when 1 mol of bromine is 2 2 2 Received 30 July 2017 used but with 2 mols the product is the polybromide, [AsPh Br ] [Br ], containing the previously 2 2 2 8 Received in revised form 21 August 2017 + unknown [AsPh Br ] cation and a rare [(Br ) ...(Br )...(Br ) ] ensemble whose short (yet not covalent) 2 2 3 2 3 Accepted 25 August 2017 2 Br ...Br contacts have previously supported tentative description

Journal

Inorganica Chimica ActaElsevier

Published: Apr 24, 2018

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off