Supramolecular architecture of [AsPh2Br2]2[(Br3)−…(Br2)…(Br3)−] obtained by bromination of (AsPh2)2S

Supramolecular architecture of [AsPh2Br2]2[(Br3)−…(Br2)…(Br3)−] obtained by bromination... Inorganica Chimica Acta 475 (2018) 120–126 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Research paper Supramolecular architecture of [AsPh Br ] [(Br ) ...(Br )...(Br ) ] 2 2 2 3 2 3 obtained by bromination of (AsPh ) S 2 2 a,⇑ a a b Luminita Silaghi-Dumitrescu , Amr A.A. Attia , Radu Silaghi-Dumitrescu , Alexander J. Blake , D. Bryan Sowerby Department of Chemistry, Babes-Bolyai University, 1, Kogalniceanu Str., 400084 Cluj-Napoca, Romania School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom ar ti c l e i nf o ab stra ct Article history: Bromination of (AsPh ) S leads to cleavage of the sulfide bridge to give AsPh Br when 1 mol of bromine is 2 2 2 Received 30 July 2017 used but with 2 mols the product is the polybromide, [AsPh Br ] [Br ], containing the previously 2 2 2 8 Received in revised form 21 August 2017 + unknown [AsPh Br ] cation and a rare [(Br ) ...(Br )...(Br ) ] ensemble whose short (yet not covalent) 2 2 3 2 3 Accepted 25 August 2017 2 Br ...Br contacts have previously supported tentative description http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganica Chimica Acta Elsevier

Supramolecular architecture of [AsPh2Br2]2[(Br3)−…(Br2)…(Br3)−] obtained by bromination of (AsPh2)2S

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0020-1693
eISSN
1873-3255
D.O.I.
10.1016/j.ica.2017.08.052
Publisher site
See Article on Publisher Site

Abstract

Inorganica Chimica Acta 475 (2018) 120–126 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Research paper Supramolecular architecture of [AsPh Br ] [(Br ) ...(Br )...(Br ) ] 2 2 2 3 2 3 obtained by bromination of (AsPh ) S 2 2 a,⇑ a a b Luminita Silaghi-Dumitrescu , Amr A.A. Attia , Radu Silaghi-Dumitrescu , Alexander J. Blake , D. Bryan Sowerby Department of Chemistry, Babes-Bolyai University, 1, Kogalniceanu Str., 400084 Cluj-Napoca, Romania School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom ar ti c l e i nf o ab stra ct Article history: Bromination of (AsPh ) S leads to cleavage of the sulfide bridge to give AsPh Br when 1 mol of bromine is 2 2 2 Received 30 July 2017 used but with 2 mols the product is the polybromide, [AsPh Br ] [Br ], containing the previously 2 2 2 8 Received in revised form 21 August 2017 + unknown [AsPh Br ] cation and a rare [(Br ) ...(Br )...(Br ) ] ensemble whose short (yet not covalent) 2 2 3 2 3 Accepted 25 August 2017 2 Br ...Br contacts have previously supported tentative description

Journal

Inorganica Chimica ActaElsevier

Published: Apr 24, 2018

References

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