Two new metal–organic frameworks [Mn3(MMA)2(INA)2]n (1) and [Cu2(FA)(INA)3(H2O)]n (2, FA = formate) were prepared solvothermally by using mixed methylmalonic acid (H2MMA) and isonicotinic acid (HINA) as the initial reactants. Single-crystal X-ray diffraction analyses reveal that complex 1 has a 3D framework structure consisting of 2D [Mn3] layer units and INA connector, and 2 owns a 2D pillar-layered structure constituted of mononuclear-Cu(II)-based 2D layer unit and paddle-wheel dinuclear Cu(II) cluster-based pillared linker, which further interspersed with each other to form a 3-fold interpenetrated framework with a (48.62)-SP topology. The magnetic studies show that 1 displays antiferromagnetic ordering at low temperature, and a strong antiferromagnetic interaction exists in 2.
Journal of Solid State Chemistry – Elsevier
Published: Aug 1, 2018
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