Journal of Colloid and Interface Science 502 (2017) 210–218 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Regular Article Solubilisation of oils in aqueous solutions of a random cationic copolymer a a a,1 a a b Jonathan C. Pegg , Adam Czajka , Gavin Hazell , Christopher Hill , Jocelyn Peach , Sarah E. Rogers , a,⇑ Julian Eastoe School of Chemistry, University of Bristol, Cantock’s Close, Bristol BS8 1TS, UK ISIS-STFC, Rutherford Appleton Laboratory, Chilton, Oxon OX11 0QX, UK graphical a bstract DMAEMA-rich hydrophilic 'interface' MMA-predominant hydrophobic 'core' Spheroidal polymer Oil swollen aggregates aggregates ar ti c l e i nf o ab stra ct Article history: Hypothesis: Reports of random copolymers capable of solubilising hydrophobic oils are rare. This is pri- Received 5 April 2017 marily because random copolymers are unlikely to self-assemble into suitable aggregates (or micelles) in Revised 27 April 2017 water. A random copolymer with a ‘‘blocky” (or lumpy) microstructure may have potential to solubilise Accepted 28 April 2017 hydrophobic oils in water. This type of polymer would have advantages over block copolymers which are Available online 2 May 2017 more laborious and costly to synthesise. Experiments: The
Journal of Colloid and Interface Science – Elsevier
Published: Sep 15, 2017
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