Inorganica Chimica Acta 475 (2018) 90–97 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Solid-state structure and solution behaviour of organomercury(II) compounds containing 2-(Me NCH )C H - moieties. Supramolecular 2 2 6 4 aspects a,b,1 a,1 a a,⇑ Oana Cadar , Alpar Pöllnitz , Dragos Ma˘rgineanu , Cristian Silvestru Departamentul de Chimie, Centrul de Chimie Supramoleculara˘ Organica˘ si Organometalica˘ (CCSOOM), Facultatea de Chimie si Inginerie Chimica˘, Universitatea Babes-Bolyai, 400028 Cluj-Napoca, Romania INCDO-INOE 2000, Research Institute for Analytical Instrumentation, 400293 Cluj-Napoca, Romania ar ti c l e i nf o ab stra ct Article history: The reaction of [2-(Me NCH )C H ]HgCl (1) with NH Br and KI gave the analogous bromide (2) and iodide 2 2 6 4 4 Received 30 July 2017 (3), respectively. To investigate the competitive coordination to the mercury centre of the nitrogen atom Received in revised form 29 August 2017 of the pendant arm and the donor atoms of a potentially chelating anionic ligand the dithiocarbamates Accepted 1 September 2017 [2-(Me NCH )C H ]HgS(S)CNR [R = Me (4), Et (5)] were prepared by reacting 1 with Na[S CNR ]nH O 2 2 6 4 2 2 2 2
Inorganica Chimica Acta – Elsevier
Published: Apr 24, 2018
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