Solid-state structure and solution behaviour of organomercury(II) compounds containing 2-(Me2NCH2)C6H4- moieties. Supramolecular aspects

Solid-state structure and solution behaviour of organomercury(II) compounds containing... Inorganica Chimica Acta 475 (2018) 90–97 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Solid-state structure and solution behaviour of organomercury(II) compounds containing 2-(Me NCH )C H - moieties. Supramolecular 2 2 6 4 aspects a,b,1 a,1 a a,⇑ Oana Cadar , Alpar Pöllnitz , Dragos Ma˘rgineanu , Cristian Silvestru Departamentul de Chimie, Centrul de Chimie Supramoleculara˘ Organica˘ si Organometalica˘ (CCSOOM), Facultatea de Chimie si Inginerie Chimica˘, Universitatea Babes-Bolyai, 400028 Cluj-Napoca, Romania INCDO-INOE 2000, Research Institute for Analytical Instrumentation, 400293 Cluj-Napoca, Romania ar ti c l e i nf o ab stra ct Article history: The reaction of [2-(Me NCH )C H ]HgCl (1) with NH Br and KI gave the analogous bromide (2) and iodide 2 2 6 4 4 Received 30 July 2017 (3), respectively. To investigate the competitive coordination to the mercury centre of the nitrogen atom Received in revised form 29 August 2017 of the pendant arm and the donor atoms of a potentially chelating anionic ligand the dithiocarbamates Accepted 1 September 2017 [2-(Me NCH )C H ]HgS(S)CNR [R = Me (4), Et (5)] were prepared by reacting 1 with Na[S CNR ]nH O 2 2 6 4 2 2 2 2 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganica Chimica Acta Elsevier

Solid-state structure and solution behaviour of organomercury(II) compounds containing 2-(Me2NCH2)C6H4- moieties. Supramolecular aspects

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0020-1693
eISSN
1873-3255
D.O.I.
10.1016/j.ica.2017.09.002
Publisher site
See Article on Publisher Site

Abstract

Inorganica Chimica Acta 475 (2018) 90–97 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Solid-state structure and solution behaviour of organomercury(II) compounds containing 2-(Me NCH )C H - moieties. Supramolecular 2 2 6 4 aspects a,b,1 a,1 a a,⇑ Oana Cadar , Alpar Pöllnitz , Dragos Ma˘rgineanu , Cristian Silvestru Departamentul de Chimie, Centrul de Chimie Supramoleculara˘ Organica˘ si Organometalica˘ (CCSOOM), Facultatea de Chimie si Inginerie Chimica˘, Universitatea Babes-Bolyai, 400028 Cluj-Napoca, Romania INCDO-INOE 2000, Research Institute for Analytical Instrumentation, 400293 Cluj-Napoca, Romania ar ti c l e i nf o ab stra ct Article history: The reaction of [2-(Me NCH )C H ]HgCl (1) with NH Br and KI gave the analogous bromide (2) and iodide 2 2 6 4 4 Received 30 July 2017 (3), respectively. To investigate the competitive coordination to the mercury centre of the nitrogen atom Received in revised form 29 August 2017 of the pendant arm and the donor atoms of a potentially chelating anionic ligand the dithiocarbamates Accepted 1 September 2017 [2-(Me NCH )C H ]HgS(S)CNR [R = Me (4), Et (5)] were prepared by reacting 1 with Na[S CNR ]nH O 2 2 6 4 2 2 2 2

Journal

Inorganica Chimica ActaElsevier

Published: Apr 24, 2018

References

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