Second generation O-alkyldithiocarbonates: Easy access to a new class of metalloligands

Second generation O-alkyldithiocarbonates: Easy access to a new class of metalloligands Inorganica Chimica Acta 475 (2018) 161–171 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Second generation O-alkyldithiocarbonates: Easy access to a new class of metalloligands a,⇑ a a a b Radu F. Semeniuc , Thomas J. Reamer , Kaitlyn A. Hammock , Holly B. Jones , Mark D. Smith , a,1 Kraig A. Wheeler Department of Chemistry and Biochemistry, Eastern Illinois University, Charleston, IL 61920, USA Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA article i nfo abstract Article history: The second-generation xanthate ligand 4-PyCH OCS Na, consisting of a backbone functionalized O- 2 2 Received 22 June 2017 alkyldithiocarbonate donor set, has been prepared. The reaction of this ligand with either Ph SnCl or Received in revised form 27 August 2017 (Ph P) CuNO yields the neutral monometallic complexes [4-PyCH OCS SnPh ] and [4-PyCH OCS Cu 3 2 3 2 2 3 2 2 Accepted 31 August 2017 (PPh ) ], respectively. These compounds were characterized by H NMR and UV–Vis spectroscopies, 3 2 Available online 5 September 2017 and in solid state by single crystal X-ray diffraction. The structure of [4-PyCH OCS SnPh ] consists of a 2 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganica Chimica Acta Elsevier

Second generation O-alkyldithiocarbonates: Easy access to a new class of metalloligands

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0020-1693
eISSN
1873-3255
D.O.I.
10.1016/j.ica.2017.08.062
Publisher site
See Article on Publisher Site

Abstract

Inorganica Chimica Acta 475 (2018) 161–171 Contents lists available at ScienceDirect Inorganica Chimica Acta journal homepage: www.elsevier.com/locate/ica Second generation O-alkyldithiocarbonates: Easy access to a new class of metalloligands a,⇑ a a a b Radu F. Semeniuc , Thomas J. Reamer , Kaitlyn A. Hammock , Holly B. Jones , Mark D. Smith , a,1 Kraig A. Wheeler Department of Chemistry and Biochemistry, Eastern Illinois University, Charleston, IL 61920, USA Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA article i nfo abstract Article history: The second-generation xanthate ligand 4-PyCH OCS Na, consisting of a backbone functionalized O- 2 2 Received 22 June 2017 alkyldithiocarbonate donor set, has been prepared. The reaction of this ligand with either Ph SnCl or Received in revised form 27 August 2017 (Ph P) CuNO yields the neutral monometallic complexes [4-PyCH OCS SnPh ] and [4-PyCH OCS Cu 3 2 3 2 2 3 2 2 Accepted 31 August 2017 (PPh ) ], respectively. These compounds were characterized by H NMR and UV–Vis spectroscopies, 3 2 Available online 5 September 2017 and in solid state by single crystal X-ray diffraction. The structure of [4-PyCH OCS SnPh ] consists of a 2

Journal

Inorganica Chimica ActaElsevier

Published: Apr 24, 2018

References

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