Journal of Colloid and Interface Science 516 (2018) 224–231 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Regular Article Reverse micelles enhance the formation of clathrate hydrates of hydrogen a,b,⇑ a b c a Pietro Di Proﬁo , Valentino Canale , Raimondo Germani , Simone Arca , Antonella Fontana Department of Pharmacy, University of Chieti-Pescara ‘‘G. D’Annunzio”, Via dei Vestini 31, I-66013 Chieti, Italy Center of Excellence on Innovative Nanostructured Materials (CEMIN), Department of Chemistry, Biology and Biotechnology, University of Perugia, Via Elce di Sotto 8, I-06123 Perugia, Italy RDPower s.r.l., Str. delle Campore 11/13, 05100 Terni, Italy highlights graphical a bstract A reverse micelle process was used to enhance clathrate hydrates of hydrogen. Hydrogen was stored into clathrate up to 0.5 wt% at 10 MPa. Formation kinetics was in the order of minutes. Water-insoluble co-guests were effectively used with the reverse micelle. Enhancement of hydrate formation was due to a remarkable increase of surface-to-volume ratio of the water pseudo-phase. ar ti c l e i nf o ab stra ct Article history: Hypothesis: Clathrate hydrates of hydrogen form at relatively low pressures (e.g., ca. 10 MPa) when a co- Received 23 October
Journal of Colloid and Interface Science – Elsevier
Published: Apr 15, 2018
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