Response of extracellular polymeric substances to thermal treatment in sludge dewatering process

Response of extracellular polymeric substances to thermal treatment in sludge dewatering process Sludge dewatering is an important process in municipal wastewater treatment and critically influences the subsequent transportation and disposal. Thermal treatment coupled with other chemical processes has been widely used to improve sludge dewaterability. However, information about the response of sludge extracellular polymeric substances (EPS) to thermal treatment and its role in sludge dewatering is still limited. In this work, the effects of thermal treatment on anaerobic and aerobic sludges were investigated with an emphasis on the colloid properties of released EPS in sludge dewatering process. The results indicate that sludge dewaterability became deteriorated with the increased temperature in the range of 30–170 °C, which was ascribed to the disintegration of sludge flocs and change of EPS characteristics. Disintegrated sludge induced the release of the negatively charged EPS, resulting in the weakened bridging interaction and lower compactness. After thermal treatment, the EPS with a higher average molecular weight and stretched coil configuration retained more water. In addition, difference in dewaterability between anaerobic and aerobic sludges was found to be attributed to their different contents and structures of EPS components. These results provide an insight into thermal-dependent sludge dewatering process and are useful to facilitate water-sludge separation. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Environmental Pollution Elsevier

Response of extracellular polymeric substances to thermal treatment in sludge dewatering process

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier Ltd
ISSN
0269-7491
D.O.I.
10.1016/j.envpol.2017.08.119
Publisher site
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Abstract

Sludge dewatering is an important process in municipal wastewater treatment and critically influences the subsequent transportation and disposal. Thermal treatment coupled with other chemical processes has been widely used to improve sludge dewaterability. However, information about the response of sludge extracellular polymeric substances (EPS) to thermal treatment and its role in sludge dewatering is still limited. In this work, the effects of thermal treatment on anaerobic and aerobic sludges were investigated with an emphasis on the colloid properties of released EPS in sludge dewatering process. The results indicate that sludge dewaterability became deteriorated with the increased temperature in the range of 30–170 °C, which was ascribed to the disintegration of sludge flocs and change of EPS characteristics. Disintegrated sludge induced the release of the negatively charged EPS, resulting in the weakened bridging interaction and lower compactness. After thermal treatment, the EPS with a higher average molecular weight and stretched coil configuration retained more water. In addition, difference in dewaterability between anaerobic and aerobic sludges was found to be attributed to their different contents and structures of EPS components. These results provide an insight into thermal-dependent sludge dewatering process and are useful to facilitate water-sludge separation.

Journal

Environmental PollutionElsevier

Published: Dec 1, 2017

References

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