Colloids and Surfaces A 538 (2018) 7–13 Contents lists available at ScienceDirect Colloids and Surfaces A journal homepage: www.elsevier.com/locate/colsurfa Research Paper Preparation and enhanced structural integrity of electrospun poly(ε-caprolactone)-based ﬁbers by freezing amorphous chains through thiol-ene click reaction a a a,b, a,c a d Jingxin Zhou , Yamei Liu , Tifeng Jiao , Ruirui Xing , Zhiqiang Yang , Jizhou Fan , ⁎⁎ d d, b Jianzhao Liu , Bingbing Li , Qiuming Peng Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, PR China State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, PR China State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, PR China Department of Chemistry, Science of Advanced Materials Doctoral Program, Central Michigan University, Mount Pleasant, MI 48859, USA GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: Facile preparation and UV stabilization of electrospun poly(e-caprolactone) (PCL)/2-methyl-3-(trimethoxysilyl) Poly(ε-caprolactone) propylester (M8POSS)/pentaerythritol tetrakis(3-mercaptopropionate) (PETM) composite ﬁbers via thiol-ene Electrospraying click reaction were investigated. The morphological studies clearly showed the M8POSS and PETM macromers Thiol-ene click reaction were excluded from PCL crystalline phase during electrospinning. The cross-linking reaction occurs
Colloids and Surfaces A: Physicochemical and Engineering Aspects – Elsevier
Published: Feb 5, 2018
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