Journal of Catalysis 360 (2018) 9–19 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat Porous core-shell N-doped Mo C@C nanospheres derived from inorganic-organic hybrid precursors for highly efﬁcient hydrogen evolution a a,b a,b a,b,⇑ a a,b a Jing-Qi Chi , Wen-Kun Gao , Jia-Hui Lin , Bin Dong , Jun-Feng Qin , Zi-Zhang Liu , Bin Liu , a,⇑ a Yong-Ming Chai , Chen-Guang Liu State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, PR China College of Science, China University of Petroleum (East China), Qingdao 266580, PR China article i nfo abstract 2 2 Article history: Using inorganic-organic MoO /aniline-pyrrole (MoO -Polymer) hybrids nanospheres as precursors, we 4 4 Received 23 December 2017 synthesize the porous core-shell N-doped Mo C@C nanospheres with the three advantages including por- Revised 20 January 2018 ous nanostructures, conductive substrate and N-doping, which may maximize the activity of electrocat- Accepted 22 January 2018 alysts for hydrogen evolution reaction (HER). The as-prepared Mo C@NC has the porous core-shell Available online 10 February 2018 nanospherical structure with ultraﬁne Mo C nanoparticles as core and ultrathin N-doped carbon (NC) nanolayers as shell. The aniline-pyrrole in MoO -Polymer
Journal of Catalysis – Elsevier
Published: Apr 1, 2018
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