Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 194–201 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Invited paper Photoredox-catalyzed hydroxyﬂuoroalkylation of alkene with simple ﬂuoroalkyl iodides a a a a,b, Xiaoyu Geng , Fengguirong Lin , Xiaoyang Wang , Ning Jiao State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Xue Yuan Rd. 38, Beijing, 100191, China Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai, 200062, China A R T I C L E I N F O A B S T R A C T Article history: Hydroxyﬂuoroalkylation of simple alkenes is presented with readily available ﬂuoroalkyl iodides by the Received 16 July 2017 Received in revised form 30 August 2017 virtue of photoredox catalysis in good efﬁciency and regioselectivity. This chemistry features mild Accepted 11 September 2017 condition, simple operation and good substrate scope. A variety of styrenes as well as non-activated Available online 18 September 2017 aliphatic alkenes can be selectively transformed to b-ﬂuoroalkylated alcohols. Preliminary mechanistic studies indicated a radical process with ﬂuoroalkyl radicals which were generated from reductive This paper is
Journal of Photochemistry and Photobiology A: Chemistry – Elsevier
Published: Mar 15, 2018
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