Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 212–219 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Invited paper Photophysical and ion-binding studies of a tetranuclear alkynylgold(I) isonitrile complex Frankie Chi-Ming Leung, Vivian Wing-Wah Yam Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee (Hong Kong)) and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China A R T I C L E I N F O A B S T R A C T Article history: A number of polyamide-containing multinuclear alkynylgold(I) isonitrile complexes have been designed, Received 8 August 2017 Received in revised form 1 September 2017 synthesized and characterized. The tetranuclear gold(I) complex is found to show spectroscopic Accepted 11 September 2017 responses in the presence of cadmium ions. The photophysical properties of the complex can be Available online 15 September 2017 modulated via the suppression of photo-induced electron transfer (PET) and intramolecular Au Au interactions. The binding mode of the complex has also been investigated by H NMR spectroscopy. The Dedicated to Prof. Chen-Ho Tung on the th complex is found to be highly selective towards
Journal of Photochemistry and Photobiology A: Chemistry – Elsevier
Published: Mar 15, 2018
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