Photophysical and ion-binding studies of a tetranuclear alkynylgold(I) isonitrile complex

Photophysical and ion-binding studies of a tetranuclear alkynylgold(I) isonitrile complex Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 212–219 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Invited paper Photophysical and ion-binding studies of a tetranuclear alkynylgold(I) isonitrile complex Frankie Chi-Ming Leung, Vivian Wing-Wah Yam Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee (Hong Kong)) and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China A R T I C L E I N F O A B S T R A C T Article history: A number of polyamide-containing multinuclear alkynylgold(I) isonitrile complexes have been designed, Received 8 August 2017 Received in revised form 1 September 2017 synthesized and characterized. The tetranuclear gold(I) complex is found to show spectroscopic Accepted 11 September 2017 responses in the presence of cadmium ions. The photophysical properties of the complex can be Available online 15 September 2017 modulated via the suppression of photo-induced electron transfer (PET) and intramolecular Au  Au interactions. The binding mode of the complex has also been investigated by H NMR spectroscopy. The Dedicated to Prof. Chen-Ho Tung on the th complex is found to be highly selective towards http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Photochemistry and Photobiology A: Chemistry Elsevier

Photophysical and ion-binding studies of a tetranuclear alkynylgold(I) isonitrile complex

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
1010-6030
eISSN
1873-2666
D.O.I.
10.1016/j.jphotochem.2017.09.028
Publisher site
See Article on Publisher Site

Abstract

Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 212–219 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Invited paper Photophysical and ion-binding studies of a tetranuclear alkynylgold(I) isonitrile complex Frankie Chi-Ming Leung, Vivian Wing-Wah Yam Institute of Molecular Functional Materials (Areas of Excellence Scheme, University Grants Committee (Hong Kong)) and Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China A R T I C L E I N F O A B S T R A C T Article history: A number of polyamide-containing multinuclear alkynylgold(I) isonitrile complexes have been designed, Received 8 August 2017 Received in revised form 1 September 2017 synthesized and characterized. The tetranuclear gold(I) complex is found to show spectroscopic Accepted 11 September 2017 responses in the presence of cadmium ions. The photophysical properties of the complex can be Available online 15 September 2017 modulated via the suppression of photo-induced electron transfer (PET) and intramolecular Au  Au interactions. The binding mode of the complex has also been investigated by H NMR spectroscopy. The Dedicated to Prof. Chen-Ho Tung on the th complex is found to be highly selective towards

Journal

Journal of Photochemistry and Photobiology A: ChemistryElsevier

Published: Mar 15, 2018

References

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