Phospholipids in chocolate: Structural insights and mechanistic explanations of rheological behavior by coarse-grained molecular dynamics simulations

Phospholipids in chocolate: Structural insights and mechanistic explanations of rheological... The structural properties of phospholipid layers and micelles at sucrose crystal cocoa butter interfaces were investigated by coarse-grained molecular dynamics simulations to understand the molecular mechanisms and structures vital for the chocolate conching process. Influences of the different hydrophilic head groups phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, and phosphatidic acid of lecithin phospholipids as well as influences of the degree of saturation of aliphatic chains were investigated. Phospholipid monolayers at sucrose–cocoa butter interfaces were shown to have similar molar composition as soy lecithin, indicating that all phospholipids adsorb with similar probability. Phospholipids with saturated aliphatic chains have smaller areas per lipid in the monolayer on the sucrose cocoa butter interface than unsaturated phospholipids. It was shown that phospholipids that are not adsorbed in the monolayer assemble in spherical, cylindrical, and wormlike micelles in cocoa butter, depending on the phospholipid concentration. Wormlike micelles were shown to be able to build a hydrophilic network in the cocoa butter medium. This is proposed as an explanation for the increasing yield values at higher lecithin concentrations in chocolate manufacturing which have been reported in several studies. The resulting structures of phospholipids on sucrose surfaces were related to experimental measurements from the literature. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Food Engineering Elsevier

Phospholipids in chocolate: Structural insights and mechanistic explanations of rheological behavior by coarse-grained molecular dynamics simulations

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier Ltd
ISSN
0260-8774
D.O.I.
10.1016/j.jfoodeng.2018.02.014
Publisher site
See Article on Publisher Site

Abstract

The structural properties of phospholipid layers and micelles at sucrose crystal cocoa butter interfaces were investigated by coarse-grained molecular dynamics simulations to understand the molecular mechanisms and structures vital for the chocolate conching process. Influences of the different hydrophilic head groups phosphatidylcholine, phosphatidylethanolamine, phosphatidylinositol, and phosphatidic acid of lecithin phospholipids as well as influences of the degree of saturation of aliphatic chains were investigated. Phospholipid monolayers at sucrose–cocoa butter interfaces were shown to have similar molar composition as soy lecithin, indicating that all phospholipids adsorb with similar probability. Phospholipids with saturated aliphatic chains have smaller areas per lipid in the monolayer on the sucrose cocoa butter interface than unsaturated phospholipids. It was shown that phospholipids that are not adsorbed in the monolayer assemble in spherical, cylindrical, and wormlike micelles in cocoa butter, depending on the phospholipid concentration. Wormlike micelles were shown to be able to build a hydrophilic network in the cocoa butter medium. This is proposed as an explanation for the increasing yield values at higher lecithin concentrations in chocolate manufacturing which have been reported in several studies. The resulting structures of phospholipids on sucrose surfaces were related to experimental measurements from the literature.

Journal

Journal of Food EngineeringElsevier

Published: Jul 1, 2018

References

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