Oxidation by H2O2 of bezothiophene and dibenzothiophene over different polyoxometalate catalysts in the frame of ultrasound and mixing assisted oxidative desulfurization

Oxidation by H2O2 of bezothiophene and dibenzothiophene over different polyoxometalate catalysts... Fuel 180 (2016) 127–136 Contents lists available at ScienceDirect Fuel journal homepage: www.elsevier.com/locate/fuel Full Length Article Oxidation by H O of bezothiophene and dibenzothiophene over 2 2 different polyoxometalate catalysts in the frame of ultrasound and mixing assisted oxidative desulfurization a a a b,⇑ Angelo Earvin Sy Choi , Susan Roces , Nathaniel Dugos , Meng-Wei Wan Chemical Engineering Department, De La Salle University, 2401 Taft Ave, Manila 0922, Philippines Department of Environmental Resource Management, Chia-Nan University of Pharmacy and Science, Tainan 71710, Taiwan highl i ghts graphical a bstrac t Oxidation process follows the pseudo-first order kinetics and Arrhenius equation. NaPW/H O system best oxidizes 2 2 benzothiophene and dibenzothiophene. Utilizing both ultrasonicator and high shear mixer showed comparable performance. Results showed better oxidation rate and activation energy than conventional ODS. article i nfo abstract Article history: Desulfurization involves the removal of refractory sulfur compounds in fossil-fuel derived oils. In this Received 7 September 2015 study, an ultrasound and mixing assisted oxidative desulfurization of synthetic oil containing sulfur com- Received in revised form 7 March 2016 pounds of benzothiophene and dibenzothiophene were carried out using different polyoxometalate cat- Accepted 5 April 2016 alysts, H O oxidant and a http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Fuel Elsevier

Oxidation by H2O2 of bezothiophene and dibenzothiophene over different polyoxometalate catalysts in the frame of ultrasound and mixing assisted oxidative desulfurization

Loading next page...
 
/lp/elsevier/oxidation-by-h2o2-of-bezothiophene-and-dibenzothiophene-over-different-LMe6MX7WNE
Publisher
Elsevier
Copyright
Copyright © 2016 Elsevier Ltd
ISSN
0016-2361
D.O.I.
10.1016/j.fuel.2016.04.014
Publisher site
See Article on Publisher Site

Abstract

Fuel 180 (2016) 127–136 Contents lists available at ScienceDirect Fuel journal homepage: www.elsevier.com/locate/fuel Full Length Article Oxidation by H O of bezothiophene and dibenzothiophene over 2 2 different polyoxometalate catalysts in the frame of ultrasound and mixing assisted oxidative desulfurization a a a b,⇑ Angelo Earvin Sy Choi , Susan Roces , Nathaniel Dugos , Meng-Wei Wan Chemical Engineering Department, De La Salle University, 2401 Taft Ave, Manila 0922, Philippines Department of Environmental Resource Management, Chia-Nan University of Pharmacy and Science, Tainan 71710, Taiwan highl i ghts graphical a bstrac t Oxidation process follows the pseudo-first order kinetics and Arrhenius equation. NaPW/H O system best oxidizes 2 2 benzothiophene and dibenzothiophene. Utilizing both ultrasonicator and high shear mixer showed comparable performance. Results showed better oxidation rate and activation energy than conventional ODS. article i nfo abstract Article history: Desulfurization involves the removal of refractory sulfur compounds in fossil-fuel derived oils. In this Received 7 September 2015 study, an ultrasound and mixing assisted oxidative desulfurization of synthetic oil containing sulfur com- Received in revised form 7 March 2016 pounds of benzothiophene and dibenzothiophene were carried out using different polyoxometalate cat- Accepted 5 April 2016 alysts, H O oxidant and a

Journal

FuelElsevier

Published: Sep 15, 2016

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create lists to
organize your research

Export lists, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off