On the luminescence of Bi3+ pairs in oxidic compounds

On the luminescence of Bi3+ pairs in oxidic compounds An empirical equation is introduced to calculate the absorption/excitation energy of Bi3+ pairs in oxidic compounds from the knowledge of their crystal structure. The method is based on recent reports that describe the optical processes within the pair as resulting from an intervalence charge transfer of the type Bi3+, Bi3+ → Bi2+, Bi4+. The data are used to locate the vacuum referred binding energy of the electron in the 2P1/2 ground state of Bi2+ ions in few oxidic compounds. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Luminescence Elsevier

On the luminescence of Bi3+ pairs in oxidic compounds

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier B.V.
ISSN
0022-2313
eISSN
1872-7883
D.O.I.
10.1016/j.jlumin.2018.01.052
Publisher site
See Article on Publisher Site

Abstract

An empirical equation is introduced to calculate the absorption/excitation energy of Bi3+ pairs in oxidic compounds from the knowledge of their crystal structure. The method is based on recent reports that describe the optical processes within the pair as resulting from an intervalence charge transfer of the type Bi3+, Bi3+ → Bi2+, Bi4+. The data are used to locate the vacuum referred binding energy of the electron in the 2P1/2 ground state of Bi2+ ions in few oxidic compounds.

Journal

Journal of LuminescenceElsevier

Published: May 1, 2018

References

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