We report on the behavior of new sulfonamide based dithiocarbamates towards unusual rhenium(V) precursors featuring the [ReN]2+ core. Reactions proceed by means of a bis-substitution of the ligand, resulting in the formation of a dianionic rhenium(V) complex of the type [ReN(SS)2]2−. The spectroscopic characterization data as well as the crystal structure of the phenyl derivative is reported here for the first time and compared with theoretical calculations. Gas phase DFT investigations involving several different available basis sets were also employed for the first time to treat the electronic configuration of the inorganic cores involving Re(V) nitrides.
Inorganica Chimica Acta – Elsevier
Published: Apr 24, 2018
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