We report on the behavior of new sulfonamide based dithiocarbamates towards unusual rhenium(V) precursors featuring the [ReN]2+ core. Reactions proceed by means of a bis-substitution of the ligand, resulting in the formation of a dianionic rhenium(V) complex of the type [ReN(SS)2]2−. The spectroscopic characterization data as well as the crystal structure of the phenyl derivative is reported here for the first time and compared with theoretical calculations. Gas phase DFT investigations involving several different available basis sets were also employed for the first time to treat the electronic configuration of the inorganic cores involving Re(V) nitrides.
Inorganica Chimica Acta – Elsevier
Published: Apr 24, 2018
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera