Nitrogen-doped carbon decorated Cu2NiSnS4 microflowers as superior anode materials for long-life lithium-ion batteries

Nitrogen-doped carbon decorated Cu2NiSnS4 microflowers as superior anode materials for long-life... Nitrogen-doped carbon (NC) decorated Cu2NiSnS4 (CNTS) microflower composites (NC@CNTS) were fabricated through a facile solvothermal and pyrrole polymerization with further annealing treatment. The NC@CNTS composites possessed a three-dimension (3D) microflower-like hierarchical structure. The unique microflower structure of NC@CNTS composites exhibited remarkable electrochemical performance as electrode materials for long life lithium ion batteries. The as-prepared composites had a stable and reversible capacity that reached 943 mA h g−1 after 160 cycles at a current rate of 0.1 A g−1. It showed satisfactory cycle stability and rate capability even at 2 A g−1, and specific capacity stabilized at 288 mA g−1 after 1000 cycles. The present facile and cost-effective strategy can be applied for the synthesis of other transition metal sulfide nanomaterials for energy storage and conversion applications. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Solid State Chemistry Elsevier

Nitrogen-doped carbon decorated Cu2NiSnS4 microflowers as superior anode materials for long-life lithium-ion batteries

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier Inc.
ISSN
0022-4596
eISSN
1095-726X
D.O.I.
10.1016/j.jssc.2018.02.021
Publisher site
See Article on Publisher Site

Abstract

Nitrogen-doped carbon (NC) decorated Cu2NiSnS4 (CNTS) microflower composites (NC@CNTS) were fabricated through a facile solvothermal and pyrrole polymerization with further annealing treatment. The NC@CNTS composites possessed a three-dimension (3D) microflower-like hierarchical structure. The unique microflower structure of NC@CNTS composites exhibited remarkable electrochemical performance as electrode materials for long life lithium ion batteries. The as-prepared composites had a stable and reversible capacity that reached 943 mA h g−1 after 160 cycles at a current rate of 0.1 A g−1. It showed satisfactory cycle stability and rate capability even at 2 A g−1, and specific capacity stabilized at 288 mA g−1 after 1000 cycles. The present facile and cost-effective strategy can be applied for the synthesis of other transition metal sulfide nanomaterials for energy storage and conversion applications.

Journal

Journal of Solid State ChemistryElsevier

Published: May 1, 2018

References

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