Molybdenum-substituted polyoxometalate as stable shuttle redox mediator for visible light driven Z-scheme water splitting system

Molybdenum-substituted polyoxometalate as stable shuttle redox mediator for visible light driven... Journal of Photochemistry and Photobiology A: Chemistry 356 (2018) 347–354 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal homepa ge: www.elsev ier.com/locate/jphotochem Molybdenum-substituted polyoxometalate as stable shuttle redox mediator for visible light driven Z-scheme water splitting system a a a a a,b, Yukari Iwase , Osamu Tomita , Hiroki Naito , Masanobu Higashi , Ryu Abe * Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510, Japan CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama, 332-0012, Japan A R T I C L E I N F O A B S T R A C T Article history: VI 4 In this study, a Mo-substituted Keggin-type polyoxometalate [SiW Mo O ] was examined as a Received 21 November 2017 11 40 Received in revised form 22 December 2017 shuttle redox mediator in Z-scheme water splitting, and its electrochemical and chemical stability were VI 4 V 5 Accepted 24 December 2017 also investigated. The redox cycle of [SiW Mo O ] /[SiW Mo O ] , which corresponds to the 11 40 11 40 VI V Available online 27 December 2017 valence change between the incorporated Mo /Mo http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Photochemistry and Photobiology A: Chemistry Elsevier

Molybdenum-substituted polyoxometalate as stable shuttle redox mediator for visible light driven Z-scheme water splitting system

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
1010-6030
eISSN
1873-2666
D.O.I.
10.1016/j.jphotochem.2017.12.034
Publisher site
See Article on Publisher Site

Abstract

Journal of Photochemistry and Photobiology A: Chemistry 356 (2018) 347–354 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal homepa ge: www.elsev ier.com/locate/jphotochem Molybdenum-substituted polyoxometalate as stable shuttle redox mediator for visible light driven Z-scheme water splitting system a a a a a,b, Yukari Iwase , Osamu Tomita , Hiroki Naito , Masanobu Higashi , Ryu Abe * Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510, Japan CREST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama, 332-0012, Japan A R T I C L E I N F O A B S T R A C T Article history: VI 4 In this study, a Mo-substituted Keggin-type polyoxometalate [SiW Mo O ] was examined as a Received 21 November 2017 11 40 Received in revised form 22 December 2017 shuttle redox mediator in Z-scheme water splitting, and its electrochemical and chemical stability were VI 4 V 5 Accepted 24 December 2017 also investigated. The redox cycle of [SiW Mo O ] /[SiW Mo O ] , which corresponds to the 11 40 11 40 VI V Available online 27 December 2017 valence change between the incorporated Mo /Mo

Journal

Journal of Photochemistry and Photobiology A: ChemistryElsevier

Published: Apr 1, 2018

References

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