Journal of Colloid and Interface Science 461 (2016) 215–224 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Macroscopic and spectroscopic investigations on Eu(III) and Cm(III) sorption onto bayerite (b-Al(OH) ) and corundum (a-Al O ) 3 2 3 a,⇑ a a a a Tomas Kupcik , Thomas Rabung , Johannes Lützenkirchen , Nicolas Finck , Horst Geckeis , b,c Thomas Fanghänel Karlsruhe Institute of Technology, Institute for Nuclear Waste Disposal, P.O. Box 3640, 76021 Karlsruhe, Germany University of Heidelberg, Institute of Physical Chemistry, Im Neunheimer Feld 253, 69120 Heidelberg, Germany Joint Research Centre – JRC, Rue du Champs de Mars 21, 1050 Brussels, Belgium highl i ghts graphical a bstrac t Sorption studied by macroscopic (batch sorption) and microscopic (TRLFS) techniques. Similar pH dependent sorption behaviour at trace metal ion concentrations. Surface transformation of the oxide surface into an hydroxidic structure. Metal ion sorption via singly coordinated aluminol groups. article i nfo abstract Article history: The interaction of trivalent Cm and Eu with the aluminum hydroxide bayerite (b-Al(OH) ) and the alu- Received 20 May 2015 minum oxide corundum (a-Al O ) was investigated by batch sorption experiments and time resolved 2 3
Journal of Colloid and Interface Science – Elsevier
Published: Jan 1, 2016
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