Low-temperature polymerization of methyl methacrylate emulsion gels through surfactant catalysis

Low-temperature polymerization of methyl methacrylate emulsion gels through surfactant catalysis Journal of Colloid and Interface Science 461 (2016) 128–135 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Low-temperature polymerization of methyl methacrylate emulsion gels through surfactant catalysis a b c a,⇑ Tan Zhang ,GuXu , Oren Regev , Frank D. Blum Department of Chemistry, Oklahoma State University, Stillwater, OK 74078, USA Brewer Science Inc., 2401 Brewer Drive, Rolla, MO 65401, USA Department of Chemical Engineering, Ben-Gurion University of the Negev, P.O. Box 653, 84105 Beer-Sheva, Israel highlights graphical a bstract Surfactant catalysis allows AIBN- CTAB Solution + Fumed Silica initiated free radical polymerization Porous at 40 C. Surfactant partially covers silica surfaces, remainder in surfactant– polymer mixture. 40 °C Silica particle mainly covered with poly(methyl methacrylate). + AIBN Fumed silica acts as an inhibitor for 4 H free radical polymerization. MMA Porous composites were produced in the presence of fumed silica. Spherical CTAB Solution ar ti c l e i nf o ab stra ct Article history: Poly(methyl methacrylate) (PMMA)/silica/cetyltrimethylammonium bromide (CTAB) composites were Received 25 June 2015 prepared through surfactant catalyzed free radical polymerizations at 40 C. Fumed silica particles con- Revised 31 August 2015 trolled the morphology of the polymeric composites http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Colloid and Interface Science Elsevier

Low-temperature polymerization of methyl methacrylate emulsion gels through surfactant catalysis

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Publisher
Elsevier
Copyright
Copyright © 2015 Elsevier Inc.
ISSN
0021-9797
eISSN
1095-7103
D.O.I.
10.1016/j.jcis.2015.09.003
Publisher site
See Article on Publisher Site

Abstract

Journal of Colloid and Interface Science 461 (2016) 128–135 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Low-temperature polymerization of methyl methacrylate emulsion gels through surfactant catalysis a b c a,⇑ Tan Zhang ,GuXu , Oren Regev , Frank D. Blum Department of Chemistry, Oklahoma State University, Stillwater, OK 74078, USA Brewer Science Inc., 2401 Brewer Drive, Rolla, MO 65401, USA Department of Chemical Engineering, Ben-Gurion University of the Negev, P.O. Box 653, 84105 Beer-Sheva, Israel highlights graphical a bstract Surfactant catalysis allows AIBN- CTAB Solution + Fumed Silica initiated free radical polymerization Porous at 40 C. Surfactant partially covers silica surfaces, remainder in surfactant– polymer mixture. 40 °C Silica particle mainly covered with poly(methyl methacrylate). + AIBN Fumed silica acts as an inhibitor for 4 H free radical polymerization. MMA Porous composites were produced in the presence of fumed silica. Spherical CTAB Solution ar ti c l e i nf o ab stra ct Article history: Poly(methyl methacrylate) (PMMA)/silica/cetyltrimethylammonium bromide (CTAB) composites were Received 25 June 2015 prepared through surfactant catalyzed free radical polymerizations at 40 C. Fumed silica particles con- Revised 31 August 2015 trolled the morphology of the polymeric composites

Journal

Journal of Colloid and Interface ScienceElsevier

Published: Jan 1, 2016

References

  • Macromolecules
    Pilcher, S.C.; Ford, W.T.
  • J. Colloid Interface Sci.
    Xu, G.; Nambiar, R.R.; Blum, F.D.
  • Polym. Degrad. Stab.
    Garia, N.; Corrales, T.; Guzman, J.; Tiemblo, P.

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