Journal of Colloid and Interface Science 461 (2016) 128–135 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Low-temperature polymerization of methyl methacrylate emulsion gels through surfactant catalysis a b c a,⇑ Tan Zhang ,GuXu , Oren Regev , Frank D. Blum Department of Chemistry, Oklahoma State University, Stillwater, OK 74078, USA Brewer Science Inc., 2401 Brewer Drive, Rolla, MO 65401, USA Department of Chemical Engineering, Ben-Gurion University of the Negev, P.O. Box 653, 84105 Beer-Sheva, Israel highlights graphical a bstract Surfactant catalysis allows AIBN- CTAB Solution + Fumed Silica initiated free radical polymerization Porous at 40 C. Surfactant partially covers silica surfaces, remainder in surfactant– polymer mixture. 40 °C Silica particle mainly covered with poly(methyl methacrylate). + AIBN Fumed silica acts as an inhibitor for 4 H free radical polymerization. MMA Porous composites were produced in the presence of fumed silica. Spherical CTAB Solution ar ti c l e i nf o ab stra ct Article history: Poly(methyl methacrylate) (PMMA)/silica/cetyltrimethylammonium bromide (CTAB) composites were Received 25 June 2015 prepared through surfactant catalyzed free radical polymerizations at 40 C. Fumed silica particles con- Revised 31 August 2015 trolled the morphology of the polymeric composites
Journal of Colloid and Interface Science – Elsevier
Published: Jan 1, 2016
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