Kinetics of Hg° oxidation over a V 2 O 5 /MoO 3 /TiO 2 catalyst: Experimental and modelling study under DeNO X inactive conditions

Kinetics of Hg° oxidation over a V 2 O 5 /MoO 3 /TiO 2 catalyst: Experimental and modelling... Applied Catalysis B: Environmental 193 (2016) 121–132 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j ourna l h om epage: www.elsevier.com/locate/apcatb Kinetics of Hg oxidation over a V O /MoO /TiO catalyst: 2 5 3 2 Experimental and modelling study under DeNO inactive conditions a b b a,∗ Nicola Usberti , Silvia Alcove Clave , Michael Nash , Alessandra Beretta Dipartimento di Energia, Politecnico di Milano, via La Masa 34, 20156 Milano, Italy Johnson Matthey, Technology Center, Sonning Common, RG4 9NH, United Kingdom a r t i c l e i n f o a b s t r a c t Article history: In this work, a kinetic study of mercury oxidation over a commercial plate-type V/Mo/Ti/O catalyst was Received 14 January 2016 addressed by investigating the effects of key operating variables (temperature, HCl and Hg concentra- Received in revised form 24 March 2016 tion). The study was performed under reference DeNO -inactive conditions, that is in the absence of NO , X X Accepted 30 March 2016 NH , SO , recognizing that surface coverage effects can greatly affect the kinetics of this complex reacting 3 X Available online 1 April 2016 system. Aim of http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Applied Catalysis B: Environmental Elsevier

Kinetics of Hg° oxidation over a V 2 O 5 /MoO 3 /TiO 2 catalyst: Experimental and modelling study under DeNO X inactive conditions

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Publisher
Elsevier
Copyright
Copyright © 2016 Elsevier B.V.
ISSN
0926-3373
D.O.I.
10.1016/j.apcatb.2016.03.071
Publisher site
See Article on Publisher Site

Abstract

Applied Catalysis B: Environmental 193 (2016) 121–132 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j ourna l h om epage: www.elsevier.com/locate/apcatb Kinetics of Hg oxidation over a V O /MoO /TiO catalyst: 2 5 3 2 Experimental and modelling study under DeNO inactive conditions a b b a,∗ Nicola Usberti , Silvia Alcove Clave , Michael Nash , Alessandra Beretta Dipartimento di Energia, Politecnico di Milano, via La Masa 34, 20156 Milano, Italy Johnson Matthey, Technology Center, Sonning Common, RG4 9NH, United Kingdom a r t i c l e i n f o a b s t r a c t Article history: In this work, a kinetic study of mercury oxidation over a commercial plate-type V/Mo/Ti/O catalyst was Received 14 January 2016 addressed by investigating the effects of key operating variables (temperature, HCl and Hg concentra- Received in revised form 24 March 2016 tion). The study was performed under reference DeNO -inactive conditions, that is in the absence of NO , X X Accepted 30 March 2016 NH , SO , recognizing that surface coverage effects can greatly affect the kinetics of this complex reacting 3 X Available online 1 April 2016 system. Aim of

Journal

Applied Catalysis B: EnvironmentalElsevier

Published: Sep 15, 2016

References

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