•New CO2BOLs consisting of DBN, TDB or BTMG in 1-hexanol medium have been developed for CO2 capture.•Intrinsic reaction rate of these systems were obtained from stopped flow experiments.•In addition, quantum chemical calculations by using B3LYP, MP2 and CCSD methods were performed.•Both experimental and theoretical investigations support single step termolecular reaction mechanism.•The developed systems have distinct advantages over conventional amines such as MEA and DEA.
International Journal of Greenhouse Gas Control – Elsevier
Published: Jun 1, 2016
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