Identification and quantification of gases emitted during abuse tests by overcharge of a commercial Li-ion battery

Identification and quantification of gases emitted during abuse tests by overcharge of a... As hazardous situations can occur during the life of a Li-ion battery, it is of great importance to understand its behavior under abusive conditions (mechanical, thermal or electrical). In particular, the study of overcharge, which consists of forcing a current through the cell, can be very helpful in improving battery safety. Very few studies in the literature have focused on the chemical reaction mechanism responsible for failure during overcharge. This is, however, of great interest because a Li-ion battery can produce reactions in a sealed container and is thus a highly reactive system. Here, experimental approaches are employed to understand the reaction mechanisms that occur during overcharge testing. Experiments consist of studying the overcharge kinetics of a commercial battery at an initial state of charge of 100%. The battery is maintained in a known volume and gaseous samples are withdrawn both at the end of the test and continuously during the test. The main gaseous species are then identified and quantified by gas phase chromatography coupled with mass spectrometry and FTIR spectroscopy. This experimental study is completed by a numerical investigation to determine the combustion parameters of the exhaust gases using a detailed reaction mechanism associated with a numerical code. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Power Sources Elsevier

Identification and quantification of gases emitted during abuse tests by overcharge of a commercial Li-ion battery

14 pages
Read Article

Loading next page...
 
/lp/elsevier/identification-and-quantification-of-gases-emitted-during-abuse-tests-9dghUtWJc4
Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier B.V.
ISSN
0378-7753
DOI
10.1016/j.jpowsour.2018.03.034
Publisher site
See Article on Publisher Site

Abstract

As hazardous situations can occur during the life of a Li-ion battery, it is of great importance to understand its behavior under abusive conditions (mechanical, thermal or electrical). In particular, the study of overcharge, which consists of forcing a current through the cell, can be very helpful in improving battery safety. Very few studies in the literature have focused on the chemical reaction mechanism responsible for failure during overcharge. This is, however, of great interest because a Li-ion battery can produce reactions in a sealed container and is thus a highly reactive system. Here, experimental approaches are employed to understand the reaction mechanisms that occur during overcharge testing. Experiments consist of studying the overcharge kinetics of a commercial battery at an initial state of charge of 100%. The battery is maintained in a known volume and gaseous samples are withdrawn both at the end of the test and continuously during the test. The main gaseous species are then identified and quantified by gas phase chromatography coupled with mass spectrometry and FTIR spectroscopy. This experimental study is completed by a numerical investigation to determine the combustion parameters of the exhaust gases using a detailed reaction mechanism associated with a numerical code.

Journal

Journal of Power Sources – Elsevier

Published: Jun 15, 2018

References

  • A failure modes, mechanisms, and effects analysis (FMMEA) of lithium-ion batteries
    Hendricks, C.; Williard, N.; Mathew, S.; Pecht, M.
  • Thermal runaway of commercial 18650 Li-ion batteries with LFP and NCA cathodes – impact of state of charge and overcharge
    Golubkov, A.W.; Scheikl, S.; Planteu, R.; Voitic, G.; Wiltsche, H.; Stangl, C.; Fauler, G.; Thalera, A.; Hacker, V.
  • Fire behavior of carbonates-based electrolytes used in Li-ion rechargeable batteries with a focus on the role of the LiPF6 and LiFSI salt
    Eshetu, G.G.; Bertrand, J.-P.; Lecoq, A.; Grugeon, S.; Laruelle, S.; Armand, M.; Marlair, G.
  • Flammability of Li-Ion battery electrolytes: flash point and self-extinguishing time measurements
    Hess, S.; Wohlfahrt-Mehrens, M.; Wachtler, M.
  • Gas chromatography/mass spectrometry as a suitable tool for the Li-ion battery electrolyte degradation mechanisms study
    Gachot, G.; Ribière, P.; Mathiron, D.; Grugeon, S.; Armand, M.; Leriche, J.-B.; Pilard, S.; Laruelle, S.
  • Effects on additives on thermal stability of Li ion cells
    Doughty, D.H.; Roth, E.P.; Crafts, C.C.; Nagasubramanian, G.; Henriksen, G.; Amine, K.
  • Diagnostic examination of thermally abused high-power lithium-ion cells
    Abraham, D.P.; Roth, E.P.; Kostecki, R.; MacLaren, S.; Doughty, D.H.
  • Abuse response of 18650 Li-ion Cells with different cathodes using EC: EMC/LiPF6 and EC: PC:DMC/LiPF6 electrolytes
    Roth, E.P.
  • Investigation on the fire-induced hazards of Li-ion battery cells by fire calorimetry
    Ribière, P.; Grugeon, S.; Morcrette, M.; Boyanov, S.; Laruelle, S.; Marlair, G.
  • Thermal-runaway experiments on consumer Li-ion batteries with metal-oxide and olivin-type cathodes
    Golubkov, A.W.; Fuchs, D.; Wagner, J.; Wiltsche, H.; Stangl, C.; Fauler, G.; Voitic, G.; Thaler, A.; Hacker, V.
  • Characteristics of lithium-ion batteries during fire test
    Larsson, F.; Andersson, P.; Blomqvist, P.; Lorén, A.; Mellander, B.-E.
  • An experimental study on burning behaviors of 18650 lithium ion batteries using a cone calorimeter
    Fu, Y.; Lu, S.; Li, K.; Liu, C.; Cheng, X.; Zhang, H.
  • Toxicity, a serious concern of thermal runaway from commercial Li-ion battery
    Sun, J.; Li, J.; Zhou, T.; Yang, K.; Wei, S.; Tang, N.; Dang, N.; Li, H.; Qiu, X.; Chen, L.
  • Holistic methodology for characterisation of the thermally induced failure of commercially available 18650 lithium ion cells
    Lammer, M.; Königseder, A.; Hacker, V.
  • Toxic fluoride gas emissions from lithium-ion battery fires
    Larsson, F.; Andersson, P.; Blomqvist, P.; Mellander, B.-E.
  • Gas generation mechanism due to electrolyte decomposition in commercial lithium-ion cell
    Kumai, K.; Miyashiro, H.; Kobayashi, Y.; Takei, K.; Ishikawa, R.
  • Overcharge reaction of lithium-ion batteries
    Ohsaki, T.; Kishi, T.; Kuboki, T.; Takami, N.; Shimura, N.; Sato, Y.; Sekino, M.; Satoh, A.
  • Gas evolution behaviors for several cathode materials in lithium-ion batteries
    Kong, W.; Li, H.; Huang, X.; Chen, L.
  • Overcharge failure investigation of lithium-ion batteries
    Yuan, Q.F.; Zhao, F.; Wang, W.; Zhao, Y.; Liang, Z.; Yan, D.
  • Quantification of combustion hazards of thermal runaway failures in lithium-ion batteries
    Somandepalli, V.; Marr, K.; Horn, Q.
  • Physical and chemical analysis of lithium-ion battery cell-to-cell failure events inside custom fire chamber
    Spinner, N.S.; Field, C.R.; Hammond, M.H.; Williams, B.A.; Myers, K.M.; Lubrano, A.L.; Rose-Pehrsson, S.L.; Tuttle, S.G.
  • Effect of overdischarge on swelling and recharge performance of lithium ion cells
    Li, H.-F.; Gao, J.-K.; Zhang, S.-L.
  • Influence of over-discharge on the lifetime and performance of LiFePO4/graphite batteries
    Zheng, Y.; Qian, K.; Luo, D.; Li, Y.; Lu, Q.; Li, B.; He, Y.-B.; Wang, X.; Li, J.; Kang, F.
  • Gas chromatography/mass spectrometry as a suitable tool for the Li-ion battery electrolyte degradation mechanisms study
    Gachot, G.; Ribière, P.; Mathiron, D.; Grugeon, S.; Armand, M.; Leriche, J.-B.; Pilard, S.; Laruelle, S.
  • Anodic oxidation of nonaqueous electrolytes on cathode materials and current collectors for rechargeable lithium batteries
    Kanamura, K.
  • Effects of separator breakdown on abuse response of 18650 Li-ion cells
    Roth, E.P.; Doughty, D.H.; Pile, D.L.
  • A study of the overcharge reaction of lithium-ion batteries
    Leising, R.A.; Palazzo, M.J.; Takeuchi, E.S.; Takeuchi, K.J.
  • An experimental and kinetic modeling study on dimethyl carbonate (DMC) pyrolysis and combustion
    Sun, W.; Yang, B.; Hansen, N.; Westbrook, C.K.; Zhang, F.; Wang, G.; Moshammer, K.; Law, C.K.
  • CHEMKIN-II: a Fortran Chemical Kinetics Package for the Analysis of Gas-Phase Chemical Kinetics
    Kee, R.J.; Rupley, F.M.; Miller, J.A.
  • Chemical kinetic modeling of dimethyl carbonate in an opposed-flow diffusion flame
    Glaude, P.A.; Pitzb, W.J.; Thomson, M.J.
  • Experimental and kinetic study on ignition delay times of dimethyl carbonate at high temperature
    Hu, E.; Chen, Y.; Zhang, Z.; Pan, L.; Li, Q.; Cheng, Y.; Huang, Z.
  • A combustion chemistry analysis of carbonate solvents used in Li-ion batteries
    Harris, S.J.; Timmons, A.; Pitz, W.J.
  • OPPDIF: Ortran Program for Computing Opposed-flow Diffusion Flames
    Lutz, E.; Kee, R.J.; Grcar, J.F.; Rupley, F.M.

You’re reading a free preview. Subscribe to read the entire article.

Try 2 weeks free now

DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

or browse the journals available

Search

Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly

Organize

Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.

Access

Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve

Freelancer

DeepDyve

Pro

Price

FREE

$49/month
$360/year

Save searches from
Google Scholar,
PubMed

Create folders to
organize your research

Export folders, citations

Read DeepDyve articles

Abstract access only

Unlimited access to over
18 million full-text articles

Print

20 pages / month

PDF Discount

20% off

Sign up
for free
Start 14 day
Free Trial