Chemical Engineering Journal 336 (2018) 748–756 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.elsevier.com/locate/cej Functionalized HNTs nanocluster vulcanized natural rubber with high ﬁller- rubber interaction a,b a, a a a a Lijuan Chen , Zhixin Jia , Xiaohui Guo , Bangchao Zhong , Yongjun Chen , Yuanfang Luo , Demin Jia Key Lab of GD High Property and Functional Macromolecular Materials, Department of Polymer Materials and Engineering, South China University of Technology, Guangzhou 510640, PR China Guangdong Provincial Key Laboratory of Functional Soft Condensed Matter, Department of Polymeric Material and Engineering, School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, PR China GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: A novel functional rubber vulcanizator, halloysite nanotubes (HNTs) supported sulfur monochloride (HNTs-s-S) Functionalized nanoparticle is prepared by chemically bonding sulfur monochloride (S Cl ) onto HNTs surface. Through this chemical re- 2 2 Vulcanizing agent action, high concentration of sulfur is supported onto HNTs inner and outer surface. Meanwhile, the functional Halloysite nanotube-supported nanotubes can not only vulcanize the rubber without sulfur and show the lower activation energy of vulcani- Interfacial interaction zation reaction, but also improve the ﬁller-rubber interaction as a modiﬁer
Chemical Engineering Journal – Elsevier
Published: Mar 15, 2018
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