Evaluation of anion chain length impact on aqueous two phase systems formed by carboxylate anion functionalized ionic liquids

Evaluation of anion chain length impact on aqueous two phase systems formed by carboxylate anion... J. Chem. Thermodynamics 120 (2018) 88–96 Contents lists available at ScienceDirect J. Chem. Thermodynamics journal homepage: www.elsevier.com/locate/jct Evaluation of anion chain length impact on aqueous two phase systems formed by carboxylate anion functionalized ionic liquids Anusha Basaiahgari, Ramesh L. Gardas Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, India ar ti c l e i nf o ab stra ct Article history: Aqueous biphasic systems (ABS) based on ionic liquids (ILs) are considered as promising separation and Received 8 September 2017 extraction media for replacing conventional extraction systems consisting of volatile organic solvents. In Received in revised form 11 January 2018 the present work, set of ILs consisting of tetrabutylammonium cation and carboxylate anions were syn- Accepted 13 January 2018 thesised and studied for their ability to form ABS in presence of strong salting-out agent K PO at 298.15 3 4 K and atmospheric pressure. The influence of alkyl chain length of ILs’ anions on the phase splitting ability has been systematically investigated. Experimentally determined binodal curve data has been fitted to Keywords: Merchuk’s equation and corresponding fitting parameters have also been determined. Further, selected Aqueous biphasic system ternary systems have been analysed for their extraction http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png The Journal of Chemical Thermodynamics Elsevier

Evaluation of anion chain length impact on aqueous two phase systems formed by carboxylate anion functionalized ionic liquids

Loading next page...
 
/lp/elsevier/evaluation-of-anion-chain-length-impact-on-aqueous-two-phase-systems-xXLkdvnOeu
Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier Ltd
ISSN
0021-9614
eISSN
1096-3626
D.O.I.
10.1016/j.jct.2018.01.009
Publisher site
See Article on Publisher Site

Abstract

J. Chem. Thermodynamics 120 (2018) 88–96 Contents lists available at ScienceDirect J. Chem. Thermodynamics journal homepage: www.elsevier.com/locate/jct Evaluation of anion chain length impact on aqueous two phase systems formed by carboxylate anion functionalized ionic liquids Anusha Basaiahgari, Ramesh L. Gardas Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, India ar ti c l e i nf o ab stra ct Article history: Aqueous biphasic systems (ABS) based on ionic liquids (ILs) are considered as promising separation and Received 8 September 2017 extraction media for replacing conventional extraction systems consisting of volatile organic solvents. In Received in revised form 11 January 2018 the present work, set of ILs consisting of tetrabutylammonium cation and carboxylate anions were syn- Accepted 13 January 2018 thesised and studied for their ability to form ABS in presence of strong salting-out agent K PO at 298.15 3 4 K and atmospheric pressure. The influence of alkyl chain length of ILs’ anions on the phase splitting ability has been systematically investigated. Experimentally determined binodal curve data has been fitted to Keywords: Merchuk’s equation and corresponding fitting parameters have also been determined. Further, selected Aqueous biphasic system ternary systems have been analysed for their extraction

Journal

The Journal of Chemical ThermodynamicsElsevier

Published: May 1, 2018

References

You’re reading a free preview. Subscribe to read the entire article.


DeepDyve is your
personal research library

It’s your single place to instantly
discover and read the research
that matters to you.

Enjoy affordable access to
over 12 million articles from more than
10,000 peer-reviewed journals.

All for just $49/month

Explore the DeepDyve Library

Unlimited reading

Read as many articles as you need. Full articles with original layout, charts and figures. Read online, from anywhere.

Stay up to date

Keep up with your field with Personalized Recommendations and Follow Journals to get automatic updates.

Organize your research

It’s easy to organize your research with our built-in tools.

Your journals are on DeepDyve

Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.

All the latest content is available, no embargo periods.

See the journals in your area

DeepDyve Freelancer

DeepDyve Pro

Price
FREE
$49/month

$360/year
Save searches from Google Scholar, PubMed
Create lists to organize your research
Export lists, citations
Read DeepDyve articles
Abstract access only
Unlimited access to over
18 million full-text articles
Print
20 pages/month
PDF Discount
20% off