•The observed phase transformation of the 75Re matrix during operation of the cathode has no effect on the emission properties.•The metal states of Wξ− in the Ba-W cathode and Reξ− in the 75Re cathode were found.•Rhenium increases the interaction between Ba of Ba-O-M (M: matrix) complex and matrix.
Applied Surface Science – Elsevier
Published: Jan 1, 2018
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