Electrodynamical forbiddance of a strong quadrupole light-molecule interaction in fullerene C60 and its withdrawal in fullerene C70

Electrodynamical forbiddance of a strong quadrupole light-molecule interaction in fullerene C60... Chemical Physics Letters 695 (2018) 235–239 Contents lists available at ScienceDirect Chemical Physics Letters journal homepage: www.elsevier.com/locate/cplett Research paper Electrodynamical forbiddance of a strong quadrupole light-molecule interaction in fullerene C and its withdrawal in fullerene C 60 70 a b,⇑ V.P. Chelibanov , A.M. Polubotko State University of Information Technologies, Mechanics and Optics, Kronverkskii 49, 197101 Saint Petersburg, Russia A.F. Ioffe Physico-Technical Institute, Politechnicheskaya 26, 194021 Saint Petersburg, Russia article i nfo abstract Article history: It is demonstrated that in fullerene C , there is a withdrawal of an Electrodynamical forbiddance of a Received 12 December 2017 strong quadrupole light-molecule interaction, which is realized in the fullerene C . This situation occurs In final form 6 February 2018 because of the reduction of symmetry of C from the icosahedral symmetry group Y to the group D . 70 h 5h Available online 12 February 2018 The withdrawal results in appearance of the lines in the SERS spectra of C , which are forbidden in usual Raman scattering and are allowed in infrared absorption. The measured SERS spectra of C demonstrates Keywords: existence of such lines that strongly confirms our ideas about the dipole –quadrupole SERS mechanism. SERS 2018 Elsevier http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chemical Physics Letters Elsevier

Electrodynamical forbiddance of a strong quadrupole light-molecule interaction in fullerene C60 and its withdrawal in fullerene C70

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier B.V.
ISSN
0009-2614
eISSN
1873-4448
D.O.I.
10.1016/j.cplett.2018.02.010
Publisher site
See Article on Publisher Site

Abstract

Chemical Physics Letters 695 (2018) 235–239 Contents lists available at ScienceDirect Chemical Physics Letters journal homepage: www.elsevier.com/locate/cplett Research paper Electrodynamical forbiddance of a strong quadrupole light-molecule interaction in fullerene C and its withdrawal in fullerene C 60 70 a b,⇑ V.P. Chelibanov , A.M. Polubotko State University of Information Technologies, Mechanics and Optics, Kronverkskii 49, 197101 Saint Petersburg, Russia A.F. Ioffe Physico-Technical Institute, Politechnicheskaya 26, 194021 Saint Petersburg, Russia article i nfo abstract Article history: It is demonstrated that in fullerene C , there is a withdrawal of an Electrodynamical forbiddance of a Received 12 December 2017 strong quadrupole light-molecule interaction, which is realized in the fullerene C . This situation occurs In final form 6 February 2018 because of the reduction of symmetry of C from the icosahedral symmetry group Y to the group D . 70 h 5h Available online 12 February 2018 The withdrawal results in appearance of the lines in the SERS spectra of C , which are forbidden in usual Raman scattering and are allowed in infrared absorption. The measured SERS spectra of C demonstrates Keywords: existence of such lines that strongly confirms our ideas about the dipole –quadrupole SERS mechanism. SERS 2018 Elsevier

Journal

Chemical Physics LettersElsevier

Published: Mar 1, 2018

References

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