Chemical Physics Letters 695 (2018) 235–239 Contents lists available at ScienceDirect Chemical Physics Letters journal homepage: www.elsevier.com/locate/cplett Research paper Electrodynamical forbiddance of a strong quadrupole light-molecule interaction in fullerene C and its withdrawal in fullerene C 60 70 a b,⇑ V.P. Chelibanov , A.M. Polubotko State University of Information Technologies, Mechanics and Optics, Kronverkskii 49, 197101 Saint Petersburg, Russia A.F. Ioffe Physico-Technical Institute, Politechnicheskaya 26, 194021 Saint Petersburg, Russia article i nfo abstract Article history: It is demonstrated that in fullerene C , there is a withdrawal of an Electrodynamical forbiddance of a Received 12 December 2017 strong quadrupole light-molecule interaction, which is realized in the fullerene C . This situation occurs In ﬁnal form 6 February 2018 because of the reduction of symmetry of C from the icosahedral symmetry group Y to the group D . 70 h 5h Available online 12 February 2018 The withdrawal results in appearance of the lines in the SERS spectra of C , which are forbidden in usual Raman scattering and are allowed in infrared absorption. The measured SERS spectra of C demonstrates Keywords: existence of such lines that strongly conﬁrms our ideas about the dipole –quadrupole SERS mechanism. SERS 2018 Elsevier
Chemical Physics Letters – Elsevier
Published: Mar 1, 2018
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