Coordination Chemistry Reviews 361 (2018) 120–137 Contents lists available at ScienceDirect Coordination Chemistry Reviews journal homepage: www.elsevier.com/locate/ccr Review Electro and photoreduction of CO driven by manganese-carbonyl molecular catalysts 1 ⇑ Matthew Stanbury, Jean-Daniel Compain , Sylvie Chardon-Noblat Univ. Grenoble Alpes, CNRS, DCM, 38000 Grenoble, France ar ti c l e i nf o ab stra ct Article history: Manganese carbonyl complexes have become popular homogeneous catalysts for carbon dioxide electro- Received 24 November 2017 or photoreduction since the beginning of the 2010s. This article presents a comprehensive survey of all Received in revised form 18 January 2018 the Mn carbonyl systems reported during the last decade as being active catalysts for CO reduction, with Accepted 19 January 2018 a comparison of their activity, stability and selectivity under electroreduction and, for some of them, pho- Available online 21 February 2018 toreduction conditions. The development of in situ spectroelectrochemical techniques, often backed by DFT calculations, has enabled gaining more insight into the associated catalytic mechanisms and reaction Keywords: intermediates. Though manganese tricarbonyl compounds featuring a bipyridine derivative have been by CO reduction far the most studied, alternative Mn coordination spheres have recently been explored, opening a way Molecular catalysis towards new
Coordination Chemistry Reviews – Elsevier
Published: Apr 15, 2018
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