Journal of Analytical and Applied Pyrolysis 126 (2017) 357–370 Contents lists available at ScienceDirect Journal of Analytical and Applied Pyrolysis journal homepage: www.elsevier.com/locate/jaap Eﬀect of catalyst type on recyclability and decomposition mechanism of poly MARK (ethylene furanoate) biobased polyester a a b b Zoe Terzopoulou , Elisavet Karakatsianopoulou , Nejib Kasmi , Mustapha Majdoub , c a, George Z. Papageorgiou , Dimitrios N. Bikiaris Laboratory of Polymer Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-541 24, Thessaloniki, Macedonia, Greece Laboratoire des Interfaces et Matériaux Avancés, Université de Monastir, 5000 Monastir, Tunisia Chemistry Department, University of Ioannina, P.O. Box 1186, 45110 Ioannina, Greece ARTICLE I NFO ABSTRACT Keywords: In the present work, poly(ethylene furanoate) (PEF) was synthesized via two-stage melt polycondensation Poly(ethylene furanoate) process, using four diﬀerent catalysts, namely tetrabutyl titanate (TBT), titanium(IV) isopropoxide (TIS), tin(II) Catalysts 2-ethylhexanoate (TEH) and dibutyltin(IV) oxide (DBTO). In all reactions, 2,5-dimethylfuran-dicarboxylate Recyclability (DMFD), ethylene glycol (EG) (1:2 molar ratio) and 400 ppm of catalyst were used. The eﬀect of these catalysts Thermal properties on the remelting and decomposition mechanism of PEF was studied. All polyesters were remelted up to three Decomposition mechanism times, and for every melting cycle the intrinsic viscosity
Journal of Analytical and Applied Pyrolysis – Elsevier
Published: Jul 1, 2017
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