Effect of catalyst type on recyclability and decomposition mechanism of poly(ethylene furanoate) biobased polyester

Effect of catalyst type on recyclability and decomposition mechanism of poly(ethylene furanoate)... Journal of Analytical and Applied Pyrolysis 126 (2017) 357–370 Contents lists available at ScienceDirect Journal of Analytical and Applied Pyrolysis journal homepage: www.elsevier.com/locate/jaap Effect of catalyst type on recyclability and decomposition mechanism of poly MARK (ethylene furanoate) biobased polyester a a b b Zoe Terzopoulou , Elisavet Karakatsianopoulou , Nejib Kasmi , Mustapha Majdoub , c a, George Z. Papageorgiou , Dimitrios N. Bikiaris Laboratory of Polymer Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-541 24, Thessaloniki, Macedonia, Greece Laboratoire des Interfaces et Matériaux Avancés, Université de Monastir, 5000 Monastir, Tunisia Chemistry Department, University of Ioannina, P.O. Box 1186, 45110 Ioannina, Greece ARTICLE I NFO ABSTRACT Keywords: In the present work, poly(ethylene furanoate) (PEF) was synthesized via two-stage melt polycondensation Poly(ethylene furanoate) process, using four different catalysts, namely tetrabutyl titanate (TBT), titanium(IV) isopropoxide (TIS), tin(II) Catalysts 2-ethylhexanoate (TEH) and dibutyltin(IV) oxide (DBTO). In all reactions, 2,5-dimethylfuran-dicarboxylate Recyclability (DMFD), ethylene glycol (EG) (1:2 molar ratio) and 400 ppm of catalyst were used. The effect of these catalysts Thermal properties on the remelting and decomposition mechanism of PEF was studied. All polyesters were remelted up to three Decomposition mechanism times, and for every melting cycle the intrinsic viscosity http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Analytical and Applied Pyrolysis Elsevier

Effect of catalyst type on recyclability and decomposition mechanism of poly(ethylene furanoate) biobased polyester

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0165-2370
eISSN
1873-250X
D.O.I.
10.1016/j.jaap.2017.05.010
Publisher site
See Article on Publisher Site

Abstract

Journal of Analytical and Applied Pyrolysis 126 (2017) 357–370 Contents lists available at ScienceDirect Journal of Analytical and Applied Pyrolysis journal homepage: www.elsevier.com/locate/jaap Effect of catalyst type on recyclability and decomposition mechanism of poly MARK (ethylene furanoate) biobased polyester a a b b Zoe Terzopoulou , Elisavet Karakatsianopoulou , Nejib Kasmi , Mustapha Majdoub , c a, George Z. Papageorgiou , Dimitrios N. Bikiaris Laboratory of Polymer Chemistry and Technology, Department of Chemistry, Aristotle University of Thessaloniki, GR-541 24, Thessaloniki, Macedonia, Greece Laboratoire des Interfaces et Matériaux Avancés, Université de Monastir, 5000 Monastir, Tunisia Chemistry Department, University of Ioannina, P.O. Box 1186, 45110 Ioannina, Greece ARTICLE I NFO ABSTRACT Keywords: In the present work, poly(ethylene furanoate) (PEF) was synthesized via two-stage melt polycondensation Poly(ethylene furanoate) process, using four different catalysts, namely tetrabutyl titanate (TBT), titanium(IV) isopropoxide (TIS), tin(II) Catalysts 2-ethylhexanoate (TEH) and dibutyltin(IV) oxide (DBTO). In all reactions, 2,5-dimethylfuran-dicarboxylate Recyclability (DMFD), ethylene glycol (EG) (1:2 molar ratio) and 400 ppm of catalyst were used. The effect of these catalysts Thermal properties on the remelting and decomposition mechanism of PEF was studied. All polyesters were remelted up to three Decomposition mechanism times, and for every melting cycle the intrinsic viscosity

Journal

Journal of Analytical and Applied PyrolysisElsevier

Published: Jul 1, 2017

References

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