Applied Catalysis B: Environmental 235 (2018) 214–224 Contents lists available at ScienceDirect Applied Catalysis B: Environmental journal homepage: www.elsevier.com/locate/apcatb Deposition of Pd nanoparticles on TiO using a Pd(acac) precursor for 2 2 photocatalytic oxidation of CO under UV-LED irradiation a,b, a a a b,c D.S. Selishchev , N.S. Kolobov , A.V. Bukhtiyarov , E.Y. Gerasimov , A.I. Gubanov , a,b D.V. Kozlov Boreskov Institute of Catalysis, Novosibirsk 630090, Russian Federation Novosibirsk State University, Novosibirsk 630090, Russian Federation Nikolaev Institute of Inorganic Chemistry, Novosibirsk 630090, Russian Federation ARTIC L E I NF O ABSTRAC T Keywords: In this study, 0.1–4 wt.% Pd-loaded catalysts were synthesized via thermal decomposition of palladium (II) Photocatalytic oxidation acetylacetonate (Pd(acac) ) at 210–310 °C or its photodecomposition under UV-LED irradiation using anatase CO oxidation TiO as a support. The catalysts were characterized by X-ray ﬂuorescence, AAS, TEM, XPS, and CO chemi- TiO sorption analyses and tested for CO oxidation at room temperature in a batch reactor both in the absence and Pd nanoparticles presence of UV-LED irradiation. The eﬀects of the Pd(acac) decomposition method and Pd content on the dark Pd(acac) catalytic and photocatalytic activities were studied. Decomposition of Pd(acac) occurred with the formation of
Applied Catalysis B: Environmental – Elsevier
Published: Nov 5, 2018
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