J. Chem. Thermodynamics 121 (2018) 121–128 Contents lists available at ScienceDirect J. Chem. Thermodynamics journal homepage: www.elsevier.com/locate/jct Densities and interfacial tensions for fatty acid methyl esters (from methyl formate to methyl heptanoate) + water demixed mixtures at atmospheric pressure conditions a,b a b a,⇑ Irene del Pozo , Marcela Cartes , Fèlix Llovell , Andrés Mejía Departamento de Ingeniería Química, Universidad de Concepción, POB 160 – C, Correo 3, Concepción, Chile Department of Chemical Engineering and Material Science, IQS School of Engineering, Universitat Ramon Llull, Via Augusta 390, Barcelona 08017, Spain article i nfo abstract Article history: Experimental determination of mass densities and interfacial tensions (IFT) at liquid-liquid equilibrium Received 22 June 2017 (LLE) for methyl ester (FAME) demixed aqueous family (from methyl formate to methyl heptanoate) Received in revised form 29 January 2018 are reported as a function of temperature at atmospheric pressure (101.3 kPa). Mass density determina- Accepted 5 February 2018 tions are carried out in a vibrating tube densimeter, whereas a spinning drop tensiometer is used for per- Available online 10 February 2018 forming IFT measurements. Furthermore, the IFT data have been correlated by using a simpliﬁed version of the Square Gradient Theory (SSGT) as applied
The Journal of Chemical Thermodynamics – Elsevier
Published: Jun 1, 2018
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