Chemical Engineering Journal 336 (2018) 38–46 Contents lists available at ScienceDirect Chemical Engineering Journal journal homepage: www.elsevier.com/locate/cej Decomposition mechanism of the C5-PFK/CO gas mixture as an alternative gas for SF a a a a, a a b Xiaoxing Zhang ,YiLi , Shuangshuang Tian , Song Xiao , Dachang Chen , Ju Tang , Ran Zhuo School of Electrical Engineering, Wuhan University, Wuhan 430072, China Electric Power Research Institute, China Southern Power Grid, Guangzhou 510623, China GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In recent years, many scholars have been devoted to the search for environmentally friendly gas-insulated C F O/CO 5 10 2 medium to gradually replace robust greenhouse gases, such as sulfur hexaﬂuoride (SF ), which are widely used Decomposition mechanism in the power industry at this stage, and thus promote the green development of power industry. In this study, the Density functional theory decomposition characteristics of C5-PFK (C5-perﬂuoroketone), a potential environmentally friendly alternative Reactive molecular dynamics gas, were theoretically investigated. First, the bond order and Fukui functions of C5-PFK were calculated based on density functional theory, and the reactivity and stability of C5-PFK were revealed from a molecular view- point. Second, the decomposition characteristics of
Chemical Engineering Journal – Elsevier
Published: Mar 15, 2018
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