Decarboxylative fluorination of aliphatic carboxylic acids under heterogeneous delafossite AgFeO2 nanoparticle catalysis: The utilization of bimetallic cooperativity

Decarboxylative fluorination of aliphatic carboxylic acids under heterogeneous delafossite AgFeO2... Journal of Catalysis 360 (2018) 270–276 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat Decarboxylative fluorination of aliphatic carboxylic acids under heterogeneous delafossite AgFeO nanoparticle catalysis: The utilization of bimetallic cooperativity Tu V. Nguyen, Vu T. Pham, Tin V.T. Nguyen, Nam T.S. Phan, Thanh Truong Department of Chemical Engineering, HCMC University of Technology, VNU-HCM, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Viet Nam ar ti c l e i nf o ab stra ct Article history: A crystalline delafossite of silver ferrite AgFeO nanoparticles were successfully synthesized by modified Received 11 September 2017 method. Physical characterizations of the AgFeO catalyst were obtained by several techniques including Revised 22 January 2018 X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy Accepted 15 February 2018 (TEM), thermogravimetric analysis (TGA), X-ray Fluorescence (XRF), and nitrogen physisorption measure- Available online 2 March 2018 ments. The material was applied as active heterogeneous catalyst for decarboxylative fluorination of car- boxylic acids. The optimized conditions utilized the electrophilic Selectfluor reagent in acetone/H O Keywords: solvent at room temperature in 3 h. Investigation of structure/activity relationship revealed strong syn- Silver ferrite ergistic effect of iron on silver center. Subsequently, http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Catalysis Elsevier

Decarboxylative fluorination of aliphatic carboxylic acids under heterogeneous delafossite AgFeO2 nanoparticle catalysis: The utilization of bimetallic cooperativity

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier Inc.
ISSN
0021-9517
D.O.I.
10.1016/j.jcat.2018.02.018
Publisher site
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Abstract

Journal of Catalysis 360 (2018) 270–276 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat Decarboxylative fluorination of aliphatic carboxylic acids under heterogeneous delafossite AgFeO nanoparticle catalysis: The utilization of bimetallic cooperativity Tu V. Nguyen, Vu T. Pham, Tin V.T. Nguyen, Nam T.S. Phan, Thanh Truong Department of Chemical Engineering, HCMC University of Technology, VNU-HCM, 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Viet Nam ar ti c l e i nf o ab stra ct Article history: A crystalline delafossite of silver ferrite AgFeO nanoparticles were successfully synthesized by modified Received 11 September 2017 method. Physical characterizations of the AgFeO catalyst were obtained by several techniques including Revised 22 January 2018 X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy Accepted 15 February 2018 (TEM), thermogravimetric analysis (TGA), X-ray Fluorescence (XRF), and nitrogen physisorption measure- Available online 2 March 2018 ments. The material was applied as active heterogeneous catalyst for decarboxylative fluorination of car- boxylic acids. The optimized conditions utilized the electrophilic Selectfluor reagent in acetone/H O Keywords: solvent at room temperature in 3 h. Investigation of structure/activity relationship revealed strong syn- Silver ferrite ergistic effect of iron on silver center. Subsequently,

Journal

Journal of CatalysisElsevier

Published: Apr 1, 2018

References

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