Cross-linked supramolecular polymers synthesized by photo-initiated thiol-ene click reaction of supramonomers

Cross-linked supramolecular polymers synthesized by photo-initiated thiol-ene click reaction of... Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 414–418 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Cross-linked supramolecular polymers synthesized by photo-initiated thiol-ene click reaction of supramonomers Xiaoguang Liu, Bo Qin, Jiang-Fei Xu*, Zhiqiang Wang, Xi Zhang Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, PR China A R T I C L E I N F O A B S T R A C T Article history: Received 23 June 2017 Supramonomers refer to monomers fabricated via noncovalent interactions and can be polymerized Received in revised form 19 July 2017 through conventional covalent methods. In this article, we realized the fabrication of cross-linked Accepted 20 July 2017 supramolecular polymers through photo-initiated thiol-ene click reaction of quadruple hydrogen Available online 23 July 2017 bonded supramonomers. It is found that the cross-linked supramolecular polymer has a higher critical polymerization concentration than the linear supramolecular polymer, because the orientation of the Keywords: trifunctional monomer leads to cyclize at low concentrations. It is anticipated that this research can Supramolecular polymers enrich the methodology of fabricating cross-linked supramolecular polymers and provide a new Supramonomers http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Photochemistry and Photobiology A: Chemistry Elsevier

Cross-linked supramolecular polymers synthesized by photo-initiated thiol-ene click reaction of supramonomers

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
1010-6030
eISSN
1873-2666
D.O.I.
10.1016/j.jphotochem.2017.07.025
Publisher site
See Article on Publisher Site

Abstract

Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 414–418 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Cross-linked supramolecular polymers synthesized by photo-initiated thiol-ene click reaction of supramonomers Xiaoguang Liu, Bo Qin, Jiang-Fei Xu*, Zhiqiang Wang, Xi Zhang Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, PR China A R T I C L E I N F O A B S T R A C T Article history: Received 23 June 2017 Supramonomers refer to monomers fabricated via noncovalent interactions and can be polymerized Received in revised form 19 July 2017 through conventional covalent methods. In this article, we realized the fabrication of cross-linked Accepted 20 July 2017 supramolecular polymers through photo-initiated thiol-ene click reaction of quadruple hydrogen Available online 23 July 2017 bonded supramonomers. It is found that the cross-linked supramolecular polymer has a higher critical polymerization concentration than the linear supramolecular polymer, because the orientation of the Keywords: trifunctional monomer leads to cyclize at low concentrations. It is anticipated that this research can Supramolecular polymers enrich the methodology of fabricating cross-linked supramolecular polymers and provide a new Supramonomers

Journal

Journal of Photochemistry and Photobiology A: ChemistryElsevier

Published: Mar 15, 2018

References

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