Journal of Photochemistry and Photobiology A: Chemistry 355 (2018) 414–418 Contents lists available at ScienceDirect Journal of Photochemistry and Photobiology A: Chemistry journal home page : www.elsevier.com/locat e/jphotochem Cross-linked supramolecular polymers synthesized by photo-initiated thiol-ene click reaction of supramonomers Xiaoguang Liu, Bo Qin, Jiang-Fei Xu*, Zhiqiang Wang, Xi Zhang Key Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, PR China A R T I C L E I N F O A B S T R A C T Article history: Received 23 June 2017 Supramonomers refer to monomers fabricated via noncovalent interactions and can be polymerized Received in revised form 19 July 2017 through conventional covalent methods. In this article, we realized the fabrication of cross-linked Accepted 20 July 2017 supramolecular polymers through photo-initiated thiol-ene click reaction of quadruple hydrogen Available online 23 July 2017 bonded supramonomers. It is found that the cross-linked supramolecular polymer has a higher critical polymerization concentration than the linear supramolecular polymer, because the orientation of the Keywords: trifunctional monomer leads to cyclize at low concentrations. It is anticipated that this research can Supramolecular polymers enrich the methodology of fabricating cross-linked supramolecular polymers and provide a new Supramonomers
Journal of Photochemistry and Photobiology A: Chemistry – Elsevier
Published: Mar 15, 2018
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