Coherent stacking of carbon nanotubes and polymer lamellar crystals: Toward oriented hybrid arrays within network valley domains

Coherent stacking of carbon nanotubes and polymer lamellar crystals: Toward oriented hybrid... As a result of horizontal phase distribution during solvent evaporation, island-like insulating domains of poly(methyl methacrylate) and network valleys of semiconductive poly(9,9′-dioctylfluorene) (PFO) spread through prepared films, which is accompanied with self-assembly of individual PFO-wrapped multi-walled carbon nanotubes selectively into PFO valleys. Considering the wrapping of molecular chains on nanotubes as a mixing status prevailingly preserved within valley domains, the detachment of molecular coils is viewed as a result of phase separation, which is only favorable above a critical temperature level. As the detachment of molecular coils from nanotubes is the prerequisite, the occurrence of nucleation of PFO lamellar crystals via annealing is observed to occur only within a narrow temperature range below the melting temperature. During the growth of lamellar crystals, the oriented hybrid stacking arrays with the intercalation of individual carbon nanotubes is able to evolve upon the mutual impingement between dispersed nanotubes and lamellar crystals. Nevertheless, depending on the number density of crystalline lamellae, this mutual impingement is also able to arrest the aligning process and randomize the hybrid dispersion. Based on the exploration of several influential factors, including the nanotube diameter and crystallization temperature, the interplay between nanotube dispersion and crystal growth has been elucidated as the governing mechanism for this mutual impingement within valley domains, and thus various patterns of hybrid dispersion. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Polymer Elsevier

Coherent stacking of carbon nanotubes and polymer lamellar crystals: Toward oriented hybrid arrays within network valley domains

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier Ltd
ISSN
0032-3861
D.O.I.
10.1016/j.polymer.2018.02.010
Publisher site
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Abstract

As a result of horizontal phase distribution during solvent evaporation, island-like insulating domains of poly(methyl methacrylate) and network valleys of semiconductive poly(9,9′-dioctylfluorene) (PFO) spread through prepared films, which is accompanied with self-assembly of individual PFO-wrapped multi-walled carbon nanotubes selectively into PFO valleys. Considering the wrapping of molecular chains on nanotubes as a mixing status prevailingly preserved within valley domains, the detachment of molecular coils is viewed as a result of phase separation, which is only favorable above a critical temperature level. As the detachment of molecular coils from nanotubes is the prerequisite, the occurrence of nucleation of PFO lamellar crystals via annealing is observed to occur only within a narrow temperature range below the melting temperature. During the growth of lamellar crystals, the oriented hybrid stacking arrays with the intercalation of individual carbon nanotubes is able to evolve upon the mutual impingement between dispersed nanotubes and lamellar crystals. Nevertheless, depending on the number density of crystalline lamellae, this mutual impingement is also able to arrest the aligning process and randomize the hybrid dispersion. Based on the exploration of several influential factors, including the nanotube diameter and crystallization temperature, the interplay between nanotube dispersion and crystal growth has been elucidated as the governing mechanism for this mutual impingement within valley domains, and thus various patterns of hybrid dispersion.

Journal

PolymerElsevier

Published: Mar 28, 2018

References

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