Chlorinated volatile organic compound oxidation over SO42−/Fe2O3 catalysts

Chlorinated volatile organic compound oxidation over SO42−/Fe2O3 catalysts Journal of Catalysis 360 (2018) 277–289 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat Chlorinated volatile organic compound oxidation over SO /Fe O 4 2 3 catalysts Zhen Zhang, Ju Huang, Hangqi Xia, Qiguang Dai, Yufeng Gu, Yijie Lao, Xingyi Wang Lab for Advanced Materials, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, People’s Republic of China article i nfo abstract Article history: SO /Fe O catalysts were prepared by precipitation of FeSO and Fe (SO ) and used in catalytic combus- 4 2 3 4 2 4 3 Received 28 August 2017 tion of chlorinated volatile organic compounds (CVOCs). Characterization by XRD, TEM, Raman, FT-IR, Revised 1 November 2017 2 XPS, H TPR, and NH TPD identifies SO /Fe O catalysts as the form of hematite a-Fe O . Residual 2 3 4 2 3 2 3 Accepted 22 November 2017 2 3+ SO species as chelating or bridged bidentate complexes with Fe ions provide a large amount of acid. Available online 12 January 2018 SO /Fe O catalysts present considerable activity for dichloromethane combustion, which is dependent 4 2 3 on both http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Catalysis Elsevier

Chlorinated volatile organic compound oxidation over SO42−/Fe2O3 catalysts

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier Inc.
ISSN
0021-9517
D.O.I.
10.1016/j.jcat.2017.11.024
Publisher site
See Article on Publisher Site

Abstract

Journal of Catalysis 360 (2018) 277–289 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat Chlorinated volatile organic compound oxidation over SO /Fe O 4 2 3 catalysts Zhen Zhang, Ju Huang, Hangqi Xia, Qiguang Dai, Yufeng Gu, Yijie Lao, Xingyi Wang Lab for Advanced Materials, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, People’s Republic of China article i nfo abstract Article history: SO /Fe O catalysts were prepared by precipitation of FeSO and Fe (SO ) and used in catalytic combus- 4 2 3 4 2 4 3 Received 28 August 2017 tion of chlorinated volatile organic compounds (CVOCs). Characterization by XRD, TEM, Raman, FT-IR, Revised 1 November 2017 2 XPS, H TPR, and NH TPD identifies SO /Fe O catalysts as the form of hematite a-Fe O . Residual 2 3 4 2 3 2 3 Accepted 22 November 2017 2 3+ SO species as chelating or bridged bidentate complexes with Fe ions provide a large amount of acid. Available online 12 January 2018 SO /Fe O catalysts present considerable activity for dichloromethane combustion, which is dependent 4 2 3 on both

Journal

Journal of CatalysisElsevier

Published: Apr 1, 2018

References

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