Journal of Catalysis 360 (2018) 277–289 Contents lists available at ScienceDirect Journal of Catalysis journal homepage: www.elsevier.com/locate/jcat Chlorinated volatile organic compound oxidation over SO /Fe O 4 2 3 catalysts Zhen Zhang, Ju Huang, Hangqi Xia, Qiguang Dai, Yufeng Gu, Yijie Lao, Xingyi Wang Lab for Advanced Materials, Research Institute of Industrial Catalysis, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, People’s Republic of China article i nfo abstract Article history: SO /Fe O catalysts were prepared by precipitation of FeSO and Fe (SO ) and used in catalytic combus- 4 2 3 4 2 4 3 Received 28 August 2017 tion of chlorinated volatile organic compounds (CVOCs). Characterization by XRD, TEM, Raman, FT-IR, Revised 1 November 2017 2 XPS, H TPR, and NH TPD identiﬁes SO /Fe O catalysts as the form of hematite a-Fe O . Residual 2 3 4 2 3 2 3 Accepted 22 November 2017 2 3+ SO species as chelating or bridged bidentate complexes with Fe ions provide a large amount of acid. Available online 12 January 2018 SO /Fe O catalysts present considerable activity for dichloromethane combustion, which is dependent 4 2 3 on both
Journal of Catalysis – Elsevier
Published: Apr 1, 2018
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