CexZr1−xO2 solid solutions for catalytic synthesis of dimethyl carbonate from CO2: Reaction mechanism and the effect of catalyst morphology on catalytic activity

CexZr1−xO2 solid solutions for catalytic synthesis of dimethyl carbonate from CO2: Reaction... Fuel 216 (2018) 245–254 Contents lists available at ScienceDirect Fuel journal homepage: www.elsevier.com/locate/fuel Full Length Article Ce Zr O solid solutions for catalytic synthesis of dimethyl carbonate x 1−x 2 from CO : Reaction mechanism and the effect of catalyst morphology on catalytic activity a a b a, Ashif H. Tamboli , Avinash A. Chaugule , Suresh W. Gosavi , Hern Kim Department of Energy Science and Technology, Smart Living Innovation Technology Center, Myongji University, Yongin, Gyeonggi-do 17058, Republic of Korea Department of Physics, Savitribai Phule, Pune University, Pune, Maharashtra, India GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In the development of green and sustainable processes, one-pot conversion of carbon dioxide into value-added Ceria-zirconia organic chemicals such as dimethyl carbonate (DMC) attracted much attention. In the present study, a series of Solid solutions Ce Zr O solid solutions (x = 0.25, 0.5, 0.75) having acid/base and high surface area was synthesized for x 1−x 2 Formation mechanism efficient production of DMC from CO and methanol. The as-prepared catalyst was characterized by scanning Carbon dioxide electron microscopy (SEM), high-resolution transmission electron microscope (HRTEM), Fourier-transform in- Dimethyl carbonate frared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Fuel Elsevier

CexZr1−xO2 solid solutions for catalytic synthesis of dimethyl carbonate from CO2: Reaction mechanism and the effect of catalyst morphology on catalytic activity

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier Ltd
ISSN
0016-2361
D.O.I.
10.1016/j.fuel.2017.12.008
Publisher site
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Abstract

Fuel 216 (2018) 245–254 Contents lists available at ScienceDirect Fuel journal homepage: www.elsevier.com/locate/fuel Full Length Article Ce Zr O solid solutions for catalytic synthesis of dimethyl carbonate x 1−x 2 from CO : Reaction mechanism and the effect of catalyst morphology on catalytic activity a a b a, Ashif H. Tamboli , Avinash A. Chaugule , Suresh W. Gosavi , Hern Kim Department of Energy Science and Technology, Smart Living Innovation Technology Center, Myongji University, Yongin, Gyeonggi-do 17058, Republic of Korea Department of Physics, Savitribai Phule, Pune University, Pune, Maharashtra, India GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In the development of green and sustainable processes, one-pot conversion of carbon dioxide into value-added Ceria-zirconia organic chemicals such as dimethyl carbonate (DMC) attracted much attention. In the present study, a series of Solid solutions Ce Zr O solid solutions (x = 0.25, 0.5, 0.75) having acid/base and high surface area was synthesized for x 1−x 2 Formation mechanism efficient production of DMC from CO and methanol. The as-prepared catalyst was characterized by scanning Carbon dioxide electron microscopy (SEM), high-resolution transmission electron microscope (HRTEM), Fourier-transform in- Dimethyl carbonate frared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and

Journal

FuelElsevier

Published: Mar 15, 2018

References

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