Journal of Colloid and Interface Science 516 (2018) 379–383 Contents lists available at ScienceDirect Journal of Colloid and Interface Science journal homepage: www.elsevier.com/locate/jcis Short Communication Application of novel hierarchical niobium-containing zeolites for synthesis of alkyl lactate and lactic acid a,b,⇑ a b c Agnieszka Feliczak-Guzik , Myroslav Sprynskyy , Izabela Nowak , Mietek Jaroniec , Boguslaw Buszewski Nicolaus Copernicus University in Torun, Faculty of Chemistry, 7 Gagarina Str., 87-100 Torun, Poland Adam Mickiewicz University in Poznan, Faculty of Chemistry, 89b Umultowska Str., 61-614 Poznan, Poland Kent State University Kent, Department of Chemistry and Biochemistry, OH 44242, USA graphical a bstract article i nfo abstract Article history: Novel hierarchical niobium-containing zeolites were synthesized for the ﬁrst time and applied for iso- Received 30 November 2017 merization of dihydroxyactetone to alkyl lactate and lactic acid (95–97% yield). These materials possess Revised 21 January 2018 secondary mesoporosity, thus facilitating access to active sites of the material by larger reagent mole- Accepted 24 January 2018 cules, preserving acidity and crystallinity of the zeolites. Available online 6 February 2018 2018 Elsevier Inc. All rights reserved. Keywords: Hierarchical zeolites containing niobium Lactic acid Alkyl lactate Biomass Dihydroxyactetone (DHA) Catalytic transformation of biomass and biomass-derived ﬁne
Journal of Colloid and Interface Science – Elsevier
Published: Apr 15, 2018
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