Colloids and Surfaces A 538 (2018) 711–719 Contents lists available at ScienceDirect Colloids and Surfaces A journal homepage: www.elsevier.com/locate/colsurfa A survey of the inﬂuence of EEDQ on eﬃcient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids Hai-Kuan Yang , Hong Zhao, Xiao-Min Wang, Yan-Kun Li Department of Chemistry, School of Science, North University of China, Taiyuan 030051, Shanxi, China GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In the present work, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ) was used as an eﬀective coupling Hybrid materials agent to design and synthesize a diversity of post-functionalized polyoxomolybdate (POM) hybrids based on an Polyoxometalates Anderson-type POM cluster and incorporating various organic molecules. Subsequently, the synthesized hybrids Organic-polyoxometalate hybrids were characterized via various analytical and spectroscopic techniques including FT-IR spectroscopy, ESI–MS, Post-functionalization H NMR spectroscopy, and elemental analysis. The present investigations revealed that diﬀerent factors such as Coupling agents alkyl chain length, steric eﬀect and electrophilicity had a profound eﬀect on the post-functionalization of the Anderson-type POM cluster utilizing EEDQ as the coupling agent. By extensively investigating the eﬀect of EEDQ on the eﬃcient post-functionalization of an Anderson-type POM cluster, EEDQ can be more eﬀectively utilized for post-functionalizing the POM clusters towards the future
Colloids and Surfaces A: Physicochemical and Engineering Aspects – Elsevier
Published: Feb 5, 2018
It’s your single place to instantly
discover and read the research
that matters to you.
Enjoy affordable access to
over 18 million articles from more than
15,000 peer-reviewed journals.
All for just $49/month
Query the DeepDyve database, plus search all of PubMed and Google Scholar seamlessly
Save any article or search result from DeepDyve, PubMed, and Google Scholar... all in one place.
Get unlimited, online access to over 18 million full-text articles from more than 15,000 scientific journals.
Read from thousands of the leading scholarly journals from SpringerNature, Elsevier, Wiley-Blackwell, Oxford University Press and more.
All the latest content is available, no embargo periods.
“Hi guys, I cannot tell you how much I love this resource. Incredible. I really believe you've hit the nail on the head with this site in regards to solving the research-purchase issue.”Daniel C.
“Whoa! It’s like Spotify but for academic articles.”@Phil_Robichaud
“I must say, @deepdyve is a fabulous solution to the independent researcher's problem of #access to #information.”@deepthiw
“My last article couldn't be possible without the platform @deepdyve that makes journal papers cheaper.”@JoseServera