A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids

A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type... Colloids and Surfaces A 538 (2018) 711–719 Contents lists available at ScienceDirect Colloids and Surfaces A journal homepage: www.elsevier.com/locate/colsurfa A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids Hai-Kuan Yang , Hong Zhao, Xiao-Min Wang, Yan-Kun Li Department of Chemistry, School of Science, North University of China, Taiyuan 030051, Shanxi, China GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In the present work, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ) was used as an effective coupling Hybrid materials agent to design and synthesize a diversity of post-functionalized polyoxomolybdate (POM) hybrids based on an Polyoxometalates Anderson-type POM cluster and incorporating various organic molecules. Subsequently, the synthesized hybrids Organic-polyoxometalate hybrids were characterized via various analytical and spectroscopic techniques including FT-IR spectroscopy, ESI–MS, Post-functionalization H NMR spectroscopy, and elemental analysis. The present investigations revealed that different factors such as Coupling agents alkyl chain length, steric effect and electrophilicity had a profound effect on the post-functionalization of the Anderson-type POM cluster utilizing EEDQ as the coupling agent. By extensively investigating the effect of EEDQ on the efficient post-functionalization of an Anderson-type POM cluster, EEDQ can be more effectively utilized for post-functionalizing the POM clusters towards the future http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Colloids and Surfaces A: Physicochemical and Engineering Aspects Elsevier

A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids

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Publisher
Elsevier
Copyright
Copyright © 2017 Elsevier B.V.
ISSN
0927-7757
eISSN
1873-4359
D.O.I.
10.1016/j.colsurfa.2017.11.039
Publisher site
See Article on Publisher Site

Abstract

Colloids and Surfaces A 538 (2018) 711–719 Contents lists available at ScienceDirect Colloids and Surfaces A journal homepage: www.elsevier.com/locate/colsurfa A survey of the influence of EEDQ on efficient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids Hai-Kuan Yang , Hong Zhao, Xiao-Min Wang, Yan-Kun Li Department of Chemistry, School of Science, North University of China, Taiyuan 030051, Shanxi, China GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In the present work, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ) was used as an effective coupling Hybrid materials agent to design and synthesize a diversity of post-functionalized polyoxomolybdate (POM) hybrids based on an Polyoxometalates Anderson-type POM cluster and incorporating various organic molecules. Subsequently, the synthesized hybrids Organic-polyoxometalate hybrids were characterized via various analytical and spectroscopic techniques including FT-IR spectroscopy, ESI–MS, Post-functionalization H NMR spectroscopy, and elemental analysis. The present investigations revealed that different factors such as Coupling agents alkyl chain length, steric effect and electrophilicity had a profound effect on the post-functionalization of the Anderson-type POM cluster utilizing EEDQ as the coupling agent. By extensively investigating the effect of EEDQ on the efficient post-functionalization of an Anderson-type POM cluster, EEDQ can be more effectively utilized for post-functionalizing the POM clusters towards the future

Journal

Colloids and Surfaces A: Physicochemical and Engineering AspectsElsevier

Published: Feb 5, 2018

References

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