Colloids and Surfaces A 538 (2018) 711–719 Contents lists available at ScienceDirect Colloids and Surfaces A journal homepage: www.elsevier.com/locate/colsurfa A survey of the inﬂuence of EEDQ on eﬃcient post-functionalization of an Anderson-type polyoxomolybdate towards construction of organic-inorganic hybrids Hai-Kuan Yang , Hong Zhao, Xiao-Min Wang, Yan-Kun Li Department of Chemistry, School of Science, North University of China, Taiyuan 030051, Shanxi, China GR APHICAL A BSTRACT ARTICLE I NFO ABSTRACT Keywords: In the present work, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ) was used as an eﬀective coupling Hybrid materials agent to design and synthesize a diversity of post-functionalized polyoxomolybdate (POM) hybrids based on an Polyoxometalates Anderson-type POM cluster and incorporating various organic molecules. Subsequently, the synthesized hybrids Organic-polyoxometalate hybrids were characterized via various analytical and spectroscopic techniques including FT-IR spectroscopy, ESI–MS, Post-functionalization H NMR spectroscopy, and elemental analysis. The present investigations revealed that diﬀerent factors such as Coupling agents alkyl chain length, steric eﬀect and electrophilicity had a profound eﬀect on the post-functionalization of the Anderson-type POM cluster utilizing EEDQ as the coupling agent. By extensively investigating the eﬀect of EEDQ on the eﬃcient post-functionalization of an Anderson-type POM cluster, EEDQ can be more eﬀectively utilized for post-functionalizing the POM clusters towards the future
Geoderma – Elsevier
Published: Feb 15, 2019
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