A study of the direct dimethyl ether fuel cell using alkaline anolyte

A study of the direct dimethyl ether fuel cell using alkaline anolyte The electrooxidation behavior of dimethyl ether (DME) dissolved in acidic, neutral or alkaline anolyte has been studied. The cyclic voltammetry measurements reveal that DME in alkaline anolyte demonstrates higher electrooxidation reactivity than that in acidic or neutral anolyte. With increasing the NaOH concentration in the anolyte, the electrooxidation reactivity of DME can be further improved. Direct dimethyl ether fuel cells (DDFCs) are assembled by using Nafion membrane as the electrolyte, Pt/C as the cathode catalyst, and Pt–Ru/C as the anode catalyst. It is found that the use of alkaline anolyte can significantly improve the performance of DDFCs. A maximum power density of 60 mW cm −2 has been achieved when operating the DDFC at 80 °C under ambient pressure. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Power Sources Elsevier

A study of the direct dimethyl ether fuel cell using alkaline anolyte

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Publisher
Elsevier
Copyright
Copyright © 2010 Elsevier Ltd
ISSN
0378-7753
DOI
10.1016/j.jpowsour.2010.03.073
Publisher site
See Article on Publisher Site

Abstract

The electrooxidation behavior of dimethyl ether (DME) dissolved in acidic, neutral or alkaline anolyte has been studied. The cyclic voltammetry measurements reveal that DME in alkaline anolyte demonstrates higher electrooxidation reactivity than that in acidic or neutral anolyte. With increasing the NaOH concentration in the anolyte, the electrooxidation reactivity of DME can be further improved. Direct dimethyl ether fuel cells (DDFCs) are assembled by using Nafion membrane as the electrolyte, Pt/C as the cathode catalyst, and Pt–Ru/C as the anode catalyst. It is found that the use of alkaline anolyte can significantly improve the performance of DDFCs. A maximum power density of 60 mW cm −2 has been achieved when operating the DDFC at 80 °C under ambient pressure.

Journal

Journal of Power SourcesElsevier

Published: Sep 1, 2010

References

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