A new metal-organic framework for separation of C2H2/CH4 and CO2/CH4 at room temperature

A new metal-organic framework for separation of C2H2/CH4 and CO2/CH4 at room temperature A 3D microporous metal-organic framework with open Cu2+ sites and suitable pore space, [Cu2(L)(H2O)2]·(H2O)4(DMF)8 (ZJU-15, H4L = 5,5′-(9H-carbazole-2,7-diyl)diisophthalic acid; DMF = N,N-dimethylformamide; ZJU = Zhejiang University), has been constructed and characterized. The activated ZJU-15a has three different types of cages and exhibits BET surface area of 1660m2g−1, and can separate gas mixture of C2H2/CH4 and CO2/CH4 at room temperature. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Solid State Chemistry Elsevier

A new metal-organic framework for separation of C2H2/CH4 and CO2/CH4 at room temperature

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Publisher
Elsevier
Copyright
Copyright © 2018 Elsevier Ltd
ISSN
0022-4596
eISSN
1095-726X
D.O.I.
10.1016/j.jssc.2018.01.002
Publisher site
See Article on Publisher Site

Abstract

A 3D microporous metal-organic framework with open Cu2+ sites and suitable pore space, [Cu2(L)(H2O)2]·(H2O)4(DMF)8 (ZJU-15, H4L = 5,5′-(9H-carbazole-2,7-diyl)diisophthalic acid; DMF = N,N-dimethylformamide; ZJU = Zhejiang University), has been constructed and characterized. The activated ZJU-15a has three different types of cages and exhibits BET surface area of 1660m2g−1, and can separate gas mixture of C2H2/CH4 and CO2/CH4 at room temperature.

Journal

Journal of Solid State ChemistryElsevier

Published: Apr 1, 2018

References

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