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References (7)
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The Viscosities of Aqueous Solutions Containing Metal Chelates Derived from Ethylenediaminetetraacetate1Journal of the American Chemical Society, 78
- Publisher
- Oxford University Press
- Copyright
- © 1968 The Chemical Society of Japan
- ISSN
- 0009-2673
- eISSN
- 1348-0634
- DOI
- 10.1246/bcsj.41.139
- Publisher site
- See Article on Publisher Site
Abstract
The viscosities of aqueous solutions containing cobalt complexes formed with ammonia, ethylenediamine (en), propylenediamine (pn), 2,2′-bipyridine (bip), 1, 10-phenanthroline (phen), and ethylenediaminetetraacetic acid (H4edta) were determined with a Cannon-Fenske capillary viscometer. Measurements were made in a Shibata viscosity bath maintained at 25±0.01°C. The Jones-Dole viscosity B-coefficients of Co(III) complex cations formed with NH3, en, pn, bip, and phen increase in that order. There is no significant difference between the B-coefficients of [Cobip3]3+ and [Cobip3]2+, or [Cophen3]3+ and [Cophen3]2+. On the other hand, a pronounced difference is found between the B-coefficients of [Coedta]− and [Coedta]2−. This might suggest that there is a marked difference in the structure of [Coedta]− and [Coedta]2− anions.
Journal
Bulletin of the Chemical Society of Japan – Oxford University Press
Published: Mar 27, 2006