Access the full text.
Sign up today, get DeepDyve free for 14 days.
Jae-Hee Lee, Eungu Lee, O. Joo, K. Jung (2004)
Stabilization of Ni/Al2O3 catalyst by Cu addition for CO2 reforming of methaneApplied Catalysis A-general, 269
Jiuling Chen, Yongdan Li, Zongquan Li, Xixiang Zhang (2004)
Production of COx-free hydrogen and nanocarbon by direct decomposition of undiluted methane on Ni–Cu–alumina catalystsApplied Catalysis A-general, 269
Y. Hu, E. Ruckenstein (2002)
BINARY MgO-BASED SOLID SOLUTION CATALYSTS FOR METHANE CONVERSION TO SYNGASCatalysis Reviews, 44
Z. Hou, Jing Gao, Jianzhong Guo, D. Liang, H. Lou, Xiaoming Zheng (2007)
Deactivation of Ni catalysts during methane autothermal reforming with CO2 and O2 in a fluidized-bed reactorJournal of Catalysis, 250
Jianqiang Zhu, Xiaoxi Peng, Lu Yao, Dongmei Tong, Changwei Hu (2012)
CO2 reforming of methane over Mg-promoted Ni/SiO2 catalysts: the influence of Mg precursors and impregnation sequencesCatalysis Science & Technology, 2
A. Budiman, Sang-Hoon Song, Tae-sun Chang, C. Shin, Myoung-Jae Choi (2012)
Dry Reforming of Methane Over Cobalt Catalysts: A Literature Review of Catalyst DevelopmentCatalysis Surveys from Asia, 16
Katsutoshi Nagaoka, K. Seshan, K. Aika, J. Lercher (2001)
Carbon Deposition during Carbon Dioxide Reforming of Methane—Comparison between Pt/Al2O3 and Pt/ZrO2Journal of Catalysis, 197
Chang‐jun Liu, Jingyun Ye, Jiaojun Jiang, Yun‐Xiang Pan (2011)
Progresses in the Preparation of Coke Resistant Ni‐based Catalyst for Steam and CO2 Reforming of MethaneChemCatChem, 3
M. Gárcia-Diéguez, I. Pieta, M. Herrera, M. Larrubia, L. Alemany (2010)
Improved Pt-Ni nanocatalysts for dry reforming of methaneApplied Catalysis A-general, 377
D. Slade, A. Duncan, K. Nordheden, S. Stagg-Williams (2007)
Mixed-conducting oxygen permeable ceramic membranes for the carbon dioxide reforming of methaneGreen Chemistry, 9
(2009)
Romµn-Martínez
M. Gárcia-Diéguez, E. Finocchio, M. Larrubia, L. Alemany, G. Busca (2010)
Characterization of alumina-supported Pt, Ni and PtNi alloy catalysts for the dry reforming of methaneJournal of Catalysis, 274
I. González, J. Jesús, E. Cañizales, Blas Delgado, C. Urbina (2012)
Comparison of the Surface State of Ni Nanoparticles Used for Methane Catalytic DecompositionJournal of Physical Chemistry C, 116
Şeyma Özkara-Aydınoğlu, A. Aksoylu (2011)
CO2 reforming of methane over Pt–Ni/Al2O3 catalysts: Effects of catalyst composition, and water and oxygen addition to the feedInternational Journal of Hydrogen Energy, 36
T. Hayakawa, Hideaki Harihara, A. Andersen, A. York, Kunio Suzuki, H. Yasuda, K. Takehira (1996)
A Sustainable Catalyst for the Partial Oxidation of Methane to Syngas: Ni/Ca1‐xSrxTiO3, Prepared In Situ from Perovskite PrecursorsAngewandte Chemie, 35
De Chen, K. Christensen, Ester Ochoa-Fernández, Zhixin Yu, B. Tøtdal, N. Latorre, A. Monzón, A. Holmen (2005)
Synthesis of carbon nanofibers: effects of Ni crystal size during methane decompositionJournal of Catalysis, 229
B. Pawelec, S. Damyanova, K. Arishtirova, J. Fierro, L. Petrov (2007)
Structural and surface features of PtNi catalysts for reforming of methane with CO2Applied Catalysis A-general, 323
Dalin Li, Y. Nakagawa, K. Tomishige (2011)
Methane reforming to synthesis gas over Ni catalysts modified with noble metalsApplied Catalysis A-general, 408
Dapeng Liu, Xy Quek, Wei Cheo, Raymond Lau, A. Borgna, Yanhui Yang (2009)
MCM-41 supported nickel-based bimetallic catalysts with superior stability during carbon dioxide reforming of methane: Effect of strong metal-support interactionJournal of Catalysis, 266
Mohan Jiang, W. Griffin, C. Hendrickson, P. Jaramillo, J. Vanbriesen, A. Venkatesh (2011)
Life cycle greenhouse gas emissions of Marcellus shale gasEnvironmental Research Letters, 6
Shaobin Wang, G. Lu (1998)
Role of CeO2 in Ni/CeO2–Al2O3 catalysts for carbon dioxide reforming of methaneApplied Catalysis B-environmental, 19
T. Choudhary, Vasant Choudhary (2008)
Energieeffiziente Synthesegasproduktion durch katalytische Sauerstoff-Reformierung von MethanAngewandte Chemie, 120
Xianjun Du, Dengsong Zhang, Liyi Shi, R. Gao, Jian-ping Zhang (2012)
Morphology Dependence of Catalytic Properties of Ni/CeO2 Nanostructures for Carbon Dioxide Reforming of MethaneJournal of Physical Chemistry C, 116
A. Ashcroft, A. Cheetham, Malcolm Green, P. Vernon (1991)
Partial oxidation of methane to synthesis gas using carbon dioxideNature, 352
M. Fan, A. Abdullah, S. Bhatia (2011)
Utilization of greenhouse gases through dry reforming: screening of nickel-based bimetallic catalysts and kinetic studies.ChemSusChem, 4 11
Leilei Xu, Huanling Song, Lingjun Chou (2011)
Carbon dioxide reforming of methane over ordered mesoporous NiO–Al2O3 composite oxidesCatalysis Science & Technology, 1
T. Choudhary, V. Choudhary (2008)
Energy-efficient syngas production through catalytic oxy-methane reforming reactions.Angewandte Chemie, 47 10
Bo-Qing Xu, Jun-Mei Wei, Hong Wang, Keqiang Sun, Qiming Zhu (2001)
Nano-MgO: novel preparation and application as support of Ni catalyst for CO2 reforming of methaneCatalysis Today, 68
Jianguo Zhang, Hui Wang, A. Dalai (2007)
Development of stable bimetallic catalysts for carbon dioxide reforming of methaneJournal of Catalysis, 249
Junling Lu, Baosong Fu, M. Kung, G. Xiao, J. Elam, H. Kung, P. Stair (2012)
Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer DepositionScience, 335
S. Nishimura, T. Shishido, K. Ebitani, K. Teramura, Tsunehiro Tanaka (2010)
Novel catalytic behavior of Cu/Al2O3 catalyst against daily start-up and shut-down (DSS)-like operation in the water gas shift reactionApplied Catalysis A-general, 387
S. Damyanova, B. Pawelec, K. Arishtirova, J. Fierro, Canan Sener, T. Dogu (2009)
MCM-41 supported PdNi catalysts for dry reforming of methaneApplied Catalysis B-environmental, 92
Kai Wang, Xiujin Li, Shengfu Ji, Bingyao Huang, Chengyue Li (2008)
Preparation of Ni-based metal monolithic catalysts and a study of their performance in methane reforming with CO2.ChemSusChem, 1 6
Weiping Ding, G. Meitzner, E. Iglesia (2002)
The effects of silanation of external acid sites on the structure and catalytic behavior of Mo/H-ZSM5Journal of Catalysis, 206
A. Wiltner, C. Linsmeier (2004)
Formation of endothermic carbides on iron and nickelPhysica Status Solidi (a), 201
L. Guczi, G. Stefler, O. Geszti, I. Sajó, Z. Pászti, A. Tompos, Z. Schay (2010)
Methane dry reforming with CO2: A study on surface carbon speciesApplied Catalysis A-general, 375
Heeyeon Kim, N. Jeong, S. Han (2012)
Synthesis of a catalytic support from natural cellulose fibers, and its performance in a CO2 reforming of CH4Applied Catalysis B-environmental, 113
V. González-Delacruz, R. Pereñíguez, F. Ternero, J. Holgado, A. Caballero (2011)
Modifying the Size of Nickel Metallic Particles by H2/CO Treatment in Ni/ZrO2 Methane Dry Reforming CatalystsACS Catalysis, 1
David Baudouin, U. Rodemerck, F. Krumeich, A. Mallmann, K. Szeto, H. Ménard, L. Veyre, J. Candy, P. Webb, C. Thieuleux, C. Copéret (2013)
Particle size effect in the low temperature reforming of methane by carbon dioxide on silica-supported Ni nanoparticlesJournal of Catalysis, 297
F. Menegazzo, M. Signoretto, F. Pinna, P. Canton, N. Pernicone (2012)
Optimization of bimetallic dry reforming catalysts by temperature programmed reactionApplied Catalysis A-general, 439
M. Fan, A. Abdullah, S. Bhatia (2009)
Catalytic Technology for Carbon Dioxide Reforming of Methane to Synthesis GasChemCatChem, 1
M. Bradford, M. Vannice (1999)
CO2 Reforming of CH4Catalysis Reviews-science and Engineering, 41
L. Arkatova, Oleg Pakhnutov, A. Shmakov, Yu. Naiborodenko, N. Kasatsky (2011)
Pt-implanted intermetallides as the catalysts for CH4–CO2 reformingCatalysis Today, 171
David Baudouin, K. Szeto, P. Laurent, Aimery Mallmann, B. Fenet, L. Veyre, U. Rodemerck, C. Copéret, C. Thieuleux (2012)
Nickel-silicide colloid prepared under mild conditions as a versatile Ni precursor for more efficient CO2 reforming of CH4 catalysts.Journal of the American Chemical Society, 134 51
Haiyou Wang, R. Baker (2004)
Decomposition of Methane over a Ni−Cu−MgO Catalyst to Produce Hydrogen and Carbon NanofibersJournal of Physical Chemistry B, 108
Takashi Hayakawa, Hideaki Harihara, Arnfinn Andersen, Andrew York, Kunio Suzuki, Hiroyuki Yasuda, K. Takehira (1996)
EIN BESTANDIGER KATALYSATOR FUR DIE PARTIELLE OXIDATION VON METHAN ZU SYNTHESEGAS : NI/CA1-XSRXTIO3, IN SITU AUS EINER PEROWSKITVORSTUFE HERGESTELLTAngewandte Chemie, 108
R. Bouarab, O. Chérifi, A. Auroux (2003)
Reforming of methane by CO2 in presence of cobalt- based catalystsGreen Chemistry, 5
A. Burnham, Jeongwoo Han, C. Clark, Michael Wang, J. Dunn, I. Palou-Rivera (2012)
Life-cycle greenhouse gas emissions of shale gas, natural gas, coal, and petroleum.Environmental science & technology, 46 2
D. San-Jose-Alonso, J. Juan-juan, M. Illán-Gómez, M. Román-Martínez (2009)
Ni, Co and bimetallic Ni–Co catalysts for the dry reforming of methaneApplied Catalysis A-general, 371
Joost-Willem Snoeck, G. Froment, M. Fowles (1997)
Filamentous carbon formation and gasification: Thermodynamics, driving force, nucleation, and steady-state growthJournal of Catalysis, 169
S. Takenaka, Shoji Kobayashi, H. Ogihara, K. Otsuka (2003)
Ni/SiO2 catalyst effective for methane decomposition into hydrogen and carbon nanofiberJournal of Catalysis, 217
Nannan Sun, Xia Wen, Feng Wang, Wei Wei, Yuhan Sun (2010)
Effect of pore structure on Ni catalyst for CO2 reforming of CH4Energy and Environmental Science, 3
S. Stagg-Williams, F. Noronha, Gene Fendley, D. Resasco (2000)
CO2 Reforming of CH4 over Pt/ZrO2 Catalysts Promoted with La and Ce OxidesJournal of Catalysis, 194
J. Ahmed, K. Ramanujachary, S. Lofland, Anthony Furiato, Govind Gupta, S. Shivaprasad, A. Ganguli (2008)
Bimetallic Cu–Ni nanoparticles of varying composition (CuNi3, CuNi, Cu3Ni)Colloids and Surfaces A: Physicochemical and Engineering Aspects, 331
Mizuki Tada, Shenghong Zhang, S. Malwadkar, N. Ishiguro, J. Soga, Y. Nagai, Keitaro Tezuka, H. Imoto, S. Otsuka-Yao-Matsuo, S. Ohkoshi, Y. Iwasawa (2012)
The active phase of nickel/ordered Ce2Zr2O(x) catalysts with a discontinuity (x=7-8) in methane steam reforming.Angewandte Chemie, 51 37
M. Gárcia-Diéguez, I. Pieta, M. Herrera, M. Larrubia, L. Alemany (2010)
Nanostructured Pt- and Ni-based catalysts for CO2-reforming of methaneJournal of Catalysis, 270
T. Odedairo, Jiuling Chen, Zhonghua Zhu (2013)
Metal–support interface of a novel Ni–CeO2 catalyst for dry reforming of methaneCatalysis Communications, 31
Hsiu-Wei Chen, Chi Wang, Chien-Hui Yu, L. Tseng, P. Liao (2004)
Carbon dioxide reforming of methane reaction catalyzed by stable nickel copper catalystsCatalysis Today, 97
Yang-guang Chen, K. Tomishige, K. Fujimoto (1997)
Formation and characteristic properties of carbonaceous species on nickel-magnesia solid solution catalysts during CH4CO2 reforming reactionApplied Catalysis A-general, 161
Xiao Xie, T. Otremba, P. Littlewood, R. Schomäcker, Arne Thomas (2013)
One-Pot Synthesis of Supported, Nanocrystalline Nickel Manganese Oxide for Dry Reforming of MethaneACS Catalysis, 3
Stable catalysis performance in long‐term operation is crucial for the wide‐scale industrialization of catalytic processes. The degradation of catalysts is a considerable problem for methane reforming with carbon dioxide, owing to carbon deposition on active sites and/or catalytic supports, and sintering of active components at high temperatures. With base metals and a modified alumina support, the present work has developed highly stable catalysts that operate free of coke formation and sintering of active components. Firstly, homogeneous copper‐nickel alloy nanoparticles (NPs), which have never previously been used for this purpose, were produced and then supported as catalytic centers onto alumina. The CuNi alloy catalyst with a Ni to Cu ratio of unity totally prohibits carbon deposition on active centers, while maintaining high activity for the reforming reaction. Second, the modification of alumina by coating with zirconia before supporting the CuNi alloy, drastically inhibits coke formation on the support, prevents the reaction of Cu in the alloy with alumina at high temperatures, and, therefore, promotes the stability of active alloy NPs. Additionally, after supporting the CuNi alloy NPs on zirconia‐coated alumina, the catalyst was coated with a thinner layer of zirconia to protect the CuNi NPs from sintering, while maintaining high activity. This state‐of‐the‐art catalyst is shown to be highly stable for methane reforming with carbon dioxide at high temperatures and the deactivation constant is calculated to be close to zero in a long‐term operation, even at extremely high space velocity of 120 000 mL g−1 h−1. The results are practically important to develop robust, as well as high performance, catalysts for the relevant reactions.
ChemCatChem – Wiley
Published: Dec 1, 2013
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.