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Determination of kinetic mechanisms for reactions measured with thermoanalytical instruments

Determination of kinetic mechanisms for reactions measured with thermoanalytical instruments The work considers the methods and techniques, allowing the assignment of the kinetic mechanisms to the chemical reactions evaluated from signals of thermoanalytical measurements. It describes which information about the kinetic mechanisms can be found from either model-free or model-based methods. The work considers the applicability of both methods and compares their results. The multiple-step reactions with well-separated peaks can be equally analyzed by both methods, but for overlapping peaks or for simultaneously running parallel reactions the model-free methods provide irrelevant results. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Journal of Thermal Analysis and Calorimetry Springer Journals

Determination of kinetic mechanisms for reactions measured with thermoanalytical instruments

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References (11)

Publisher
Springer Journals
Copyright
Copyright © 2012 by Akadémiai Kiadó, Budapest, Hungary
Subject
Chemistry; Measurement Science and Instrumentation; Physical Chemistry; Analytical Chemistry; Inorganic Chemistry; Polymer Sciences
ISSN
1388-6150
eISSN
1572-8943
DOI
10.1007/s10973-012-2406-3
Publisher site
See Article on Publisher Site

Abstract

The work considers the methods and techniques, allowing the assignment of the kinetic mechanisms to the chemical reactions evaluated from signals of thermoanalytical measurements. It describes which information about the kinetic mechanisms can be found from either model-free or model-based methods. The work considers the applicability of both methods and compares their results. The multiple-step reactions with well-separated peaks can be equally analyzed by both methods, but for overlapping peaks or for simultaneously running parallel reactions the model-free methods provide irrelevant results.

Journal

Journal of Thermal Analysis and Calorimetry – Springer Journals

Published: Sep 1, 2012

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