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Andy Chapman, M. Haddow, D. Wass (2011)
Frustrated Lewis pairs beyond the main group: synthesis, reactivity, and small molecule activation with cationic zirconocene-phosphinoaryloxide complexes.Journal of the American Chemical Society, 133 45
A. Wacker, Chaoguo Yan, G. Kaltenpoth, A. Ginsberg, A. Arif, R. Ernst, H. Pritzkow, W. Siebert (2002)
Metal complexes of anionic 3-borane-1-alkylimidazol-2-ylidene derivativesJournal of Organometallic Chemistry, 641
Yuetao Zhang, G. Miyake, Mallory John, L. Falivene, L. Caporaso, L. Cavallo, E. Chen (2012)
Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism.Dalton transactions, 41 30
Hung Duong, Thomas Tekavec, A. Arif, J. Louie (2004)
Reversible carboxylation of N-heterocyclic carbenes.Chemical communications, 1
(1996)
Amoureux , Solid State Nucl
Ian Casely, S. Liddle, A. Blake, Claire Wilson, P. Arnold (2007)
Tetravalent cerium carbene complexes.Chemical communications, 47
Aaron Rossini, R. Schurko (2006)
Experimental and theoretical studies of 45Sc NMR interactions in solids.Journal of the American Chemical Society, 128 32
Baolin Wang, Dun-jia Wang, Dongmei Cui, Wei-guo Gao, T. Tang, and Chen, X. Jing (2007)
Synthesis of the First Rare Earth Metal Bis(alkyl)s Bearing an Indenyl Functionalized N-Heterocyclic CarbeneOrganometallics, 26
P. Arnold, Zoë Turner, R. Bellabarba, R. Tooze (2011)
Carbon-silicon and carbon-carbon bond formation by elimination reactions at metal N-heterocyclic carbene complexes.Journal of the American Chemical Society, 133 30
(1743)
Bond Covalent M(III) radii Longest distance Corrected longest distance Average distance Corrected average distance
Hui Zhou, Wen-Zhen Zhang, Cuixia Liu, Jingping Qu, Xiao‐Bing Lu (2008)
CO2 adducts of N-heterocyclic carbenes: thermal stability and catalytic activity toward the coupling of CO2 with epoxides.The Journal of organic chemistry, 73 20
Lionel Delaude, X. Sauvage, A. Demonceau, J. Wouters (2009)
Synthesis and Catalytic Evaluation of Ruthenium−Arene Complexes Generated Using Imidazol(in)ium-2-carboxylates and DithiocarboxylatesOrganometallics, 28
M. Alba, P. Chain, P. Florian, D. Massiot (2010)
45Sc Spectroscopy of Solids: Interpretation of Quadrupole Interaction Parameters and Chemical ShiftsJournal of Physical Chemistry C, 114
Natalie Jones, S. Liddle, Claire Wilson, P. Arnold (2007)
Titanium(III) Alkoxy-N-heterocyclic Carbenes and a Safe, Low-Cost Route to TiCl3(THF)3Organometallics, 26
W. Marsden (2012)
I and J
E. Brulé, V. Guérineau, P. Vermaut, F. Prima, János Balogh, L. Maron, A. Slawin, S. Nolan, Christophe Thomas (2013)
Polymerization of cyclic esters using N-heterocyclic carbene carboxylate catalystsPolymer Chemistry, 4
Bret Ausdall, Jeremy Glass, K. Wiggins, A. Aarif, J. Louie (2009)
A systematic investigation of factors influencing the decarboxylation of imidazolium carboxylates.The Journal of organic chemistry, 74 20
D. Gibson (1996)
The Organometallic Chemistry of Carbon Dioxide.Chemical reviews, 96 6
P. Arnold, Zoë Turner, A. Germeroth, Ian Casely, G. Nichol, R. Bellabarba, R. Tooze (2013)
Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes.Dalton transactions, 42 5
Lionel Delaude, A. Demonceau, J. Wouters (2009)
Assessing the Potential of Zwitterionic NHC·CS2 Adducts for Probing the Stereoelectronic Parameters of N‐Heterocyclic CarbenesEuropean Journal of Inorganic Chemistry, 2009
Displacement ellipsoid plot of the molecular structures of 3 and 4 (50% probability ellipsoids). H atoms omitted for clarity
Cornelia Mömming, E. Otten, G. Kehr, R. Fröhlich, S. Grimme, D. Stephan, G. Erker (2009)
Reversible metal-free carbon dioxide binding by frustrated Lewis pairs.Angewandte Chemie, 48 36
O. Sereda, Amélie Blanrue, R. Wilhelm (2009)
Enantiopure imidazolinium-dithiocarboxylates as highly selective novel organocatalysts.Chemical communications, 9
J. Fackler (1934)
Inorganic SynthesesScience
U. Siemeling, Henry Memczak, C. Bruhn, Florian Vogel, Frank Träger, J. Baio, Tobias Weidner (2012)
Zwitterionic dithiocarboxylates derived from N-heterocyclic carbenes: coordination to gold surfaces.Dalton transactions, 41 10
Gomes and T
Gabriel Ménard, D. Stephan (2010)
Room temperature reduction of CO2 to methanol by Al-based frustrated Lewis pairs and ammonia borane.Journal of the American Chemical Society, 132 6
Baolin Wang, Dongmei Cui, K. Lv (2008)
Highly 3,4-selective living polymerization of isoprene with rare earth metal fluorenyl N-heterocyclic carbene precursorsMacromolecules, 41
(2013)
Electronic Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of
O. Jacquet, Xavier Frogneux, C. Gomes, T. Cantat (2013)
CO2 as a C1-building block for the catalytic methylation of aminesChemical Science, 4
E. Kolychev, T. Bannenberg, M. Freytag, C. Daniliuc, P. Jones, M. Tamm (2012)
Reactivity of a frustrated lewis pair and small-molecule activation by an isolable Arduengo carbene-B{3,5-(CF3)2C6H3}3 complex.Chemistry, 18 52
Liang Zhang, Z. Hou (2013)
N-Heterocyclic carbene (NHC)–copper-catalysed transformations of carbon dioxideChemical Science, 4
Colin Finn, S. Schnittger, L. Yellowlees, J. Love (2012)
Molecular approaches to the electrochemical reduction of carbon dioxide.Chemical communications, 48 10
Andrew Ashley, A. Thompson, D. O′Hare (2009)
Non-metal Mediated Homogeneous Hydrogenation of CO 2 to CH 3 OH
(1996)
Solid State Nucl. Magn. Reson
(2012)
Baio 90 and T. Weidner
(2009)
Angew
and P
D. Palomas, S. Holle, B. Inés, H. Bruns, R. Goddard, M. Alcarazo (2012)
Synthesis and reactivity of electron poor allenes: formation of completely organic frustrated Lewis pairs.Dalton transactions, 41 30
Michael Sgro, D. Stephan (2013)
Activation of CO2 by phosphinoamide hafnium complexes.Chemical communications, 49 26
P. Arnold, Sergey Zlatogorsky, Natalie Jones, Christopher Carmichael, S. Liddle, A. Blake, Claire Wilson (2008)
Comparisons between yttrium and titanium N-heterocyclic carbene complexes in the search for early transition metal NHC backbonding interactions.Inorganic chemistry, 47 19
Lionel Delaude (2009)
Betaine Adducts of N-Heterocyclic Carbenes : Synthesis, Properties, and ReactivityEuropean Journal of Inorganic Chemistry, 2009
A Sc NHC complex readily activates three equivalents of CO 2 showing ‘Frustrated Lewis Pair’ type reactivity with each metal–carbene bond, but whilst CS 2 is also activated by the labile carbenes, no metal involvement is observed.
Dalton Transactions – Royal Society of Chemistry
Published: Oct 11, 2013
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