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Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex A Sc NHC complex readily activates three equivalents of CO 2 showing ‘Frustrated Lewis Pair’ type reactivity with each metal–carbene bond, but whilst CS 2 is also activated by the labile carbenes, no metal involvement is observed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Dalton Transactions Royal Society of Chemistry

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

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References (42)

Publisher
Royal Society of Chemistry
Copyright
This journal is © The Royal Society of Chemistry
ISSN
1477-9226
eISSN
1477-9234
DOI
10.1039/c3dt52762j
pmid
24162511
Publisher site
See Article on Publisher Site

Abstract

A Sc NHC complex readily activates three equivalents of CO 2 showing ‘Frustrated Lewis Pair’ type reactivity with each metal–carbene bond, but whilst CS 2 is also activated by the labile carbenes, no metal involvement is observed.

Journal

Dalton TransactionsRoyal Society of Chemistry

Published: Oct 11, 2013

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