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Multilayered Langmuir–Blodgett Films of Thiol‐Substituted Ultrasmall Gold Clusters

Multilayered Langmuir–Blodgett Films of Thiol‐Substituted Ultrasmall Gold Clusters Langmuir–Blodgett (LB) deposition of thiol‐stabilized gold clusters is reported to be controllable through the action of a hydrophilic thiol in the subphase, leading to reproducible monolayer transfer. The Figure is a schematic representation of a gold cluster, denoted Au55SiOS and prepared from a precursor by ligand exchange with a oligosilsesquioxane‐based thiol derivative, with 12 thiol molecules in the ligand shell. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Advanced Materials Wiley

Multilayered Langmuir–Blodgett Films of Thiol‐Substituted Ultrasmall Gold Clusters

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References (1)

Publisher
Wiley
Copyright
Copyright © 1998 Wiley Subscription Services, Inc., A Wiley Company
ISSN
0935-9648
eISSN
1521-4095
DOI
10.1002/(SICI)1521-4095(199808)10:11<842::AID-ADMA842>3.0.CO;2-X
Publisher site
See Article on Publisher Site

Abstract

Langmuir–Blodgett (LB) deposition of thiol‐stabilized gold clusters is reported to be controllable through the action of a hydrophilic thiol in the subphase, leading to reproducible monolayer transfer. The Figure is a schematic representation of a gold cluster, denoted Au55SiOS and prepared from a precursor by ligand exchange with a oligosilsesquioxane‐based thiol derivative, with 12 thiol molecules in the ligand shell.

Journal

Advanced Materials – Wiley

Published: Aug 1, 1998

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